{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Zhang X"],"funding":["National Natural Science Foundation of China"],"pagination":["9686-9692"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9050140"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(16)"],"pubmed_abstract":["Herein we designed and synthesized mPEG/PDPA copolymers containing two 4-([2,2':6',2''-terpyridin]-4'-yl) phenyl (Tpyp) groups at the junction point of the two blocks (mPEG(-<i>b</i>-Tpyp)<sub>2</sub>-<i>b</i>-PDPA <sub><i>x</i></sub> , <i>x</i> = 23, 33, and 44). Interestingly, after a hierarchical pattern from the coordination of mPEG(-<i>b</i>-Tpyp)<sub>2</sub>-<i>b</i>-PDPA <sub><i>x</i></sub> with Ru(ii) ions followed by the self-assembly in water, 2D strip nanosheets with a monomolecular layer were obtained. In contrast, mPEG(-<i>b</i>-Tpyp)<sub>2</sub>-<i>b</i>-PDPA <sub><i>x</i></sub> without coordination self-assembled into spherical micelles in the similar condition. The formation of the rigid and charged ⋯Tpyp-Ru(ii)⋯ chain, the brush-shaped polymer architecture and the presence"],"journal":["RSC advances"],"pubmed_title":["Metallo-supramolecular complexes from mPEG/PDPA diblock copolymers and their self-assembled strip nanosheets."],"pmcid":["PMC9050140"],"funding_grant_id":["21871222"],"pubmed_authors":["Liu Y","Yan L","Liang Y","Zhang X","Wang X"],"additional_accession":[]},"is_claimable":false,"name":"Metallo-supramolecular complexes from mPEG/PDPA diblock copolymers and their self-assembled strip nanosheets.","description":"Herein we designed and synthesized mPEG/PDPA copolymers containing two 4-([2,2':6',2''-terpyridin]-4'-yl) phenyl (Tpyp) groups at the junction point of the two blocks (mPEG(-<i>b</i>-Tpyp)<sub>2</sub>-<i>b</i>-PDPA <sub><i>x</i></sub> , <i>x</i> = 23, 33, and 44). Interestingly, after a hierarchical pattern from the coordination of mPEG(-<i>b</i>-Tpyp)<sub>2</sub>-<i>b</i>-PDPA <sub><i>x</i></sub> with Ru(ii) ions followed by the self-assembly in water, 2D strip nanosheets with a monomolecular layer were obtained. In contrast, mPEG(-<i>b</i>-Tpyp)<sub>2</sub>-<i>b</i>-PDPA <sub><i>x</i></sub> without coordination self-assembled into spherical micelles in the similar condition. The formation of the rigid and charged ⋯Tpyp-Ru(ii)⋯ chain, the brush-shaped polymer architecture and the presence","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Mar","modification":"2025-04-26T15:12:59.743Z","creation":"2025-04-06T14:51:41.025Z"},"accession":"S-EPMC9050140","cross_references":{"pubmed":["35497249"],"doi":["10.1039/d0ra00431f"]}}