biostudies-literatureUnknown10(18)Wang QA Ru or Rh-catalyzed efficient and atom-economic C7 allylation of indolines with vinylcyclopropanes was developed <i>via</i> sequential C-H and C-C activation. A wide range of substrates were well tolerated to afford the corresponding allylated indolines in high yields and <i>E</i>/<i>Z</i> selectivities under microwave irradiation. The obtained allylated indolines could further undergo transformations to afford various value-added chemicals. Importantly, this reaction proceeded at room temperature under solvent-free conditions.RSC advances10883-10887https://www.ebi.ac.uk/biostudies/studies/S-EPMC9050424biostudies-literatureSolvent-free and room temperature microwave-assisted direct C7 allylation of indolines <i>via</i> sequential C-H and C-C activation.PMC9050424Shi LSong MPWang QHao XQFu LRZhu XLiu SZhi CfalseSolvent-free and room temperature microwave-assisted direct C7 allylation of indolines <i>via</i> sequential C-H and C-C activation.A Ru or Rh-catalyzed efficient and atom-economic C7 allylation of indolines with vinylcyclopropanes was developed <i>via</i> sequential C-H and C-C activation. A wide range of substrates were well tolerated to afford the corresponding allylated indolines in high yields and <i>E</i>/<i>Z</i> selectivities under microwave irradiation. The obtained allylated indolines could further undergo transformations to afford various value-added chemicals. Importantly, this reaction proceeded at room temperature under solvent-free conditions.2020-01-01T00:00:00Z2020 Mar2025-06-01T01:30:24.477Z2025-06-01T01:30:24.477ZS-EPMC90504243549290910.1039/d0ra02016h