{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Fovanna T"],"funding":["Competence Center of Energy and Mobility","Swiss National Science Foundation","Paul Scherrer Institut"],"pagination":["11507-11516"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9050498"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(19)"],"pubmed_abstract":["Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al<sub>2</sub>O<sub>3</sub> based catalyst upon impregnation with ammonium hypophosphite followed by either reduction or calcination to study the effect of phosphorous on the physico-chemical properties of the active phase. Characterization using X-ray diffraction, solid state <sup>31</sup>P nuclear magnetic resonance spectroscopy, X-ray absorption spectroscopy, temperature programmed reduction with H<sub>2</sub>, infrared spectroscopy of pyridine adsorption from the liquid phase and transmission electron microscopy indicated that phosphorous induces a high dispersion of Ru, promotes Ru reducibility and is respons"],"journal":["RSC advances"],"pubmed_title":["Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural."],"pmcid":["PMC9050498"],"funding_grant_id":["150638","206021_150638/1","206021"],"pubmed_authors":["Kambolis A","Peng G","Villa A","Krocher O","Rentsch D","Ferri D","Nachtegaal M","Fovanna T","Campisi S"],"additional_accession":[]},"is_claimable":false,"name":"Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural.","description":"Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al<sub>2</sub>O<sub>3</sub> based catalyst upon impregnation with ammonium hypophosphite followed by either reduction or calcination to study the effect of phosphorous on the physico-chemical properties of the active phase. Characterization using X-ray diffraction, solid state <sup>31</sup>P nuclear magnetic resonance spectroscopy, X-ray absorption spectroscopy, temperature programmed reduction with H<sub>2</sub>, infrared spectroscopy of pyridine adsorption from the liquid phase and transmission electron microscopy indicated that phosphorous induces a high dispersion of Ru, promotes Ru reducibility and is respons","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Mar","modification":"2025-04-05T13:23:13.426Z","creation":"2025-04-05T13:23:13.426Z"},"accession":"S-EPMC9050498","cross_references":{"pubmed":["35495338"],"doi":["10.1039/d0ra00415d"]}}