{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Muddassir M"],"funding":["Ministry of Education – Kingdom of Saudi Arabi"],"pagination":["42137-42146"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9057960"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(69)"],"pubmed_abstract":["In this study, Cu<sup>2+</sup> perchlorate complexes of 3,5-dimetylpyrazole(dmpy), namely [Cu(dmpy)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>](H<sub>2</sub>O)(ClO<sub>4</sub>)<sub>2</sub> (1), were prepared and characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), infrared (IR) spectroscopy, elemental analysis, mass spectrometry, and ultraviolet visible (UV-Vis) spectroscopy. It was determined that Cu<sup>2+</sup> coordinated to the nitrogen atoms of three dmpy molecules as well as to the oxygen atoms of two H<sub>2</sub>O molecules in a square pyramidal geometry. To balance the charge, two uncoordinated perchlorate anions and one H<sub>2</sub>O molecule were also present in the lattice. The resulting Cu<sup>2+</sup> complex was involved in extensive hydrogen bonding, w"],"journal":["RSC advances"],"pubmed_title":["A fluorescent Cu(ii) complex as a dual functional sensor for selective and sensitive detection of acetone and Cd(ii) pollutants."],"pmcid":["PMC9057960"],"funding_grant_id":["IFKSURG–1440–076"],"pubmed_authors":["Muddassir M","Alshali KA","Afzal M","Beagan A","Alarifi A","Abduh NAY"],"additional_accession":[]},"is_claimable":false,"name":"A fluorescent Cu(ii) complex as a dual functional sensor for selective and sensitive detection of acetone and Cd(ii) pollutants.","description":"In this study, Cu<sup>2+</sup> perchlorate complexes of 3,5-dimetylpyrazole(dmpy), namely [Cu(dmpy)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>](H<sub>2</sub>O)(ClO<sub>4</sub>)<sub>2</sub> (1), were prepared and characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), infrared (IR) spectroscopy, elemental analysis, mass spectrometry, and ultraviolet visible (UV-Vis) spectroscopy. It was determined that Cu<sup>2+</sup> coordinated to the nitrogen atoms of three dmpy molecules as well as to the oxygen atoms of two H<sub>2</sub>O molecules in a square pyramidal geometry. To balance the charge, two uncoordinated perchlorate anions and one H<sub>2</sub>O molecule were also present in the lattice. The resulting Cu<sup>2+</sup> complex was involved in extensive hydrogen bonding, w","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Nov","modification":"2025-04-18T14:14:09.675Z","creation":"2025-04-04T20:22:04.637Z"},"accession":"S-EPMC9057960","cross_references":{"pubmed":["35516735"],"doi":["10.1039/d0ra08073j"]}}