{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["9(6)"],"submitter":["Yao G"],"pubmed_abstract":["DMSO was found to activate arylisothiocyanates for self-nucleophilic addition. A subsequent intramolecular C-H sulfurization catalyzed by PdBr<sub>2</sub> enables access to a wide range of 2-aminobenzothiazole derivatives in moderate to good yields. This is the first example of a DMSO-mediated Pd-catalyzed synthesis of 2-aminobenzothiazoles through cyclization/C-H sulfurization of two isothiocyanates."],"journal":["RSC advances"],"pagination":["3403-3406"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9060301"],"repository":["biostudies-literature"],"pubmed_title":["DMSO-mediated palladium-catalyzed cyclization of two isothiocyanates <i>via</i> C-H sulfurization: a new route to 2-aminobenzothiazoles."],"pmcid":["PMC9060301"],"pubmed_authors":["Wang BF","Zhang ZX","Yao G","Yang S","Xu HH","Tang RY"],"additional_accession":[]},"is_claimable":false,"name":"DMSO-mediated palladium-catalyzed cyclization of two isothiocyanates <i>via</i> C-H sulfurization: a new route to 2-aminobenzothiazoles.","description":"DMSO was found to activate arylisothiocyanates for self-nucleophilic addition. A subsequent intramolecular C-H sulfurization catalyzed by PdBr<sub>2</sub> enables access to a wide range of 2-aminobenzothiazole derivatives in moderate to good yields. This is the first example of a DMSO-mediated Pd-catalyzed synthesis of 2-aminobenzothiazoles through cyclization/C-H sulfurization of two isothiocyanates.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Jan","modification":"2025-04-04T20:21:53.563Z","creation":"2025-04-04T20:21:53.563Z"},"accession":"S-EPMC9060301","cross_references":{"pubmed":["35518944"],"doi":["10.1039/c8ra09784d"]}}