{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Feng J"],"funding":["National Natural Science Foundation of China"],"pagination":["9729-9736"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9062190"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(17)"],"pubmed_abstract":["Developing cheap and efficient transition metal-based catalysts for the oxygen evolution reaction (OER) plays the key role in large-scale implementation of hydrogen production. However, there is still a lack of effective ways to tune the catalysts performance for the OER reaction from the aspect of structure design and element modulation simultaneously. Herein, a novel Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> hexagonal nanosheet has been synthesized through the coprecipitation reaction followed by subsequent vapor sulfidation. Simply mixed with carbon nanotubes (CNTs) during electrode preparation, this Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> exhibits an overpotential of 284 mV <i>vs.</i> RHE at a current density of 10 mA cm<sup>-2</sup> in 1.0 M KOH. The improved OER performance of the Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> electrode can be attributed to the electrocatalytically active sites involved in octahedral coordination structures and further activated by Cu substitution. The encouraging results provide insight into further rational design of transition metal-based electrochemical catalysts towards OER applications."],"journal":["RSC advances"],"pubmed_title":["Controlled phase evolution from Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> to Cu<sub>3</sub>Co<sub>6</sub>S<sub>8</sub> hexagonal nanosheets as oxygen evolution reaction catalysts."],"pmcid":["PMC9062190"],"funding_grant_id":["51601040","51871059","51572048"],"pubmed_authors":["Lian Z","Li Y","Feng J","Long Z","Meng Y","Fang L","Song Y"],"additional_accession":[]},"is_claimable":false,"name":"Controlled phase evolution from Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> to Cu<sub>3</sub>Co<sub>6</sub>S<sub>8</sub> hexagonal nanosheets as oxygen evolution reaction catalysts.","description":"Developing cheap and efficient transition metal-based catalysts for the oxygen evolution reaction (OER) plays the key role in large-scale implementation of hydrogen production. However, there is still a lack of effective ways to tune the catalysts performance for the OER reaction from the aspect of structure design and element modulation simultaneously. Herein, a novel Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> hexagonal nanosheet has been synthesized through the coprecipitation reaction followed by subsequent vapor sulfidation. Simply mixed with carbon nanotubes (CNTs) during electrode preparation, this Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> exhibits an overpotential of 284 mV <i>vs.</i> RHE at a current density of 10 mA cm<sup>-2</sup> in 1.0 M KOH. The improved OER performance of the Cu<sub>0.33</sub>Co<sub>0.67</sub>S<sub>2</sub> electrode can be attributed to the electrocatalytically active sites involved in octahedral coordination structures and further activated by Cu substitution. The encouraging results provide insight into further rational design of transition metal-based electrochemical catalysts towards OER applications.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Mar","modification":"2025-04-19T13:18:33.272Z","creation":"2025-04-19T13:18:33.272Z"},"accession":"S-EPMC9062190","cross_references":{"pubmed":["35520737"],"doi":["10.1039/c9ra00640k"]}}