{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Dockendorff J"],"funding":["Natural Sciences and Engineering Research Council of Canada","Deutsche Forschungsgemeinschaft","European Research Council","Government of the Russian Federation"],"pagination":["8108-8122"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9062874"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["53(18)"],"pubmed_abstract":["Arborescent copolymers with a core-shell-corona (CSC) architecture were synthesized and the topology of the molecules was challenged (constrained) through intramolecular interactions, resulting in phase separation breaking the symmetry of radial density. The inner poly(2-vinylpyridine) shell of these arborescent polystyrene-<i>g</i>-[poly(2-vinylpyridine)-<i>b</i>-polystyrene] molecules can self-assemble by binding metallic salts and acids in apolar and intermediate-polarity solvents. Upon loading with HAuCl<sub>4</sub>, the characteristics of the polymer templates govern the \"loading sites\" of the metal within the molecules. Unique morphologies were observed for the metal-loaded G0-G4 arborescent copolymers investigated, namely, spherical, toroidal, raspberry-like, spherical nanocage, and"],"journal":["Macromolecules"],"pubmed_title":["Metal Coordination Induces Phase Segregation in Amphipolar Arborescent Copolymers with a Core-Shell-Corona Architecture."],"pmcid":["PMC9062874"],"funding_grant_id":["02.A03.21.0011","695716","SFB 985"],"pubmed_authors":["Moller M","Gumerov RA","Mourran A","Gauthier M","Dockendorff J","Potemkin II"],"additional_accession":[]},"is_claimable":false,"name":"Metal Coordination Induces Phase Segregation in Amphipolar Arborescent Copolymers with a Core-Shell-Corona Architecture.","description":"Arborescent copolymers with a core-shell-corona (CSC) architecture were synthesized and the topology of the molecules was challenged (constrained) through intramolecular interactions, resulting in phase separation breaking the symmetry of radial density. The inner poly(2-vinylpyridine) shell of these arborescent polystyrene-<i>g</i>-[poly(2-vinylpyridine)-<i>b</i>-polystyrene] molecules can self-assemble by binding metallic salts and acids in apolar and intermediate-polarity solvents. Upon loading with HAuCl<sub>4</sub>, the characteristics of the polymer templates govern the \"loading sites\" of the metal within the molecules. Unique morphologies were observed for the metal-loaded G0-G4 arborescent copolymers investigated, namely, spherical, toroidal, raspberry-like, spherical nanocage, and","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Sep","modification":"2025-04-25T18:05:55.835Z","creation":"2025-04-25T18:05:55.835Z"},"accession":"S-EPMC9062874","cross_references":{"pubmed":["35516458"],"doi":["10.1021/acs.macromol.0c00778"]}}