{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["9(28)"],"submitter":["Ma Y"],"pubmed_abstract":["In the presence of the amino acid histidine, an inorganic-organic hybrid metal sulfite, Zn<sub>2</sub>(SO<sub>3</sub>)<sub>2</sub>(C<sub>6</sub>N<sub>3</sub>O<sub>2</sub>H<sub>9</sub>)<sub>2</sub>·H<sub>2</sub>O (1), has been prepared under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 shows a 2D layer framework built up from a classical second building unit (S4R), and bridged histidine molecule. Notably, it is the first report of a metal sulfite in the presence of an amino acid molecule. A 1D H-bonding array can be constructed by the H-bonding interaction between histidine molecules and sulfite groups. Moreover, a new function of metal sulfite for proton conduction was investigated by alternating-current impedance analysis. The results demonstrate that "],"journal":["RSC advances"],"pagination":["16130-16135"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9064370"],"repository":["biostudies-literature"],"pubmed_title":["High proton conductivity behavior in a 2D metal sulfite constructed from a histidine ligand."],"pmcid":["PMC9064370"],"pubmed_authors":["Yin Y","Zheng Z","Yang Y","Xiu Z","Ma Y","Huang L","Wang X","Bi Y"],"additional_accession":[]},"is_claimable":false,"name":"High proton conductivity behavior in a 2D metal sulfite constructed from a histidine ligand.","description":"In the presence of the amino acid histidine, an inorganic-organic hybrid metal sulfite, Zn<sub>2</sub>(SO<sub>3</sub>)<sub>2</sub>(C<sub>6</sub>N<sub>3</sub>O<sub>2</sub>H<sub>9</sub>)<sub>2</sub>·H<sub>2</sub>O (1), has been prepared under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 shows a 2D layer framework built up from a classical second building unit (S4R), and bridged histidine molecule. Notably, it is the first report of a metal sulfite in the presence of an amino acid molecule. A 1D H-bonding array can be constructed by the H-bonding interaction between histidine molecules and sulfite groups. Moreover, a new function of metal sulfite for proton conduction was investigated by alternating-current impedance analysis. The results demonstrate that ","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 May","modification":"2025-04-25T17:32:06.9Z","creation":"2025-04-06T05:51:50.294Z"},"accession":"S-EPMC9064370","cross_references":{"pubmed":["35521406"],"doi":["10.1039/c9ra01584a"]}}