{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["9(30)"],"submitter":["Nagata T"],"pubmed_abstract":["<i>N</i>,<i>N</i>-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. <i>N</i>,<i>N-</i>Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions."],"journal":["RSC advances"],"pagination":["17425-17431"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9064576"],"repository":["biostudies-literature"],"pubmed_title":["Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes."],"pmcid":["PMC9064576"],"pubmed_authors":["Inoue T","Ishimoto S","Suzuki T","Nakamichi S","Nagata T","Oka H","Lin X","Obora Y","Kondo R"],"additional_accession":[]},"is_claimable":false,"name":"Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.","description":"<i>N</i>,<i>N</i>-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. <i>N</i>,<i>N-</i>Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 May","modification":"2025-04-05T13:24:32.432Z","creation":"2025-04-05T13:24:32.432Z"},"accession":"S-EPMC9064576","cross_references":{"pubmed":["35519839"],"doi":["10.1039/c9ra02895a"]}}