biostudies-literatureUnknown9(30)Nagata T<i>N</i>,<i>N</i>-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. <i>N</i>,<i>N-</i>Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.RSC advances17425-17431https://www.ebi.ac.uk/biostudies/studies/S-EPMC9064576biostudies-literatureDimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.PMC9064576Inoue TIshimoto SSuzuki TNakamichi SNagata TOka HLin XObora YKondo RfalseDimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.<i>N</i>,<i>N</i>-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. <i>N</i>,<i>N-</i>Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.2019-01-01T00:00:00Z2019 May2025-04-05T13:24:32.432Z2025-04-05T13:24:32.432ZS-EPMC90645763551983910.1039/c9ra02895a