{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["9(31)"],"submitter":["Gadde K"],"funding":["Universiteit Antwerpen","Fonds Wetenschappelijk Onderzoek"],"pubmed_abstract":["The iron(iii)-catalyzed efficient strategy for the synthesis of α-substituted homoallylamines was accomplished <i>via</i> a cationic 2-aza-Cope rearrangement of aldimines, generated <i>in situ</i> by condensation of commercially available aldehydes and easily synthesizable 1,1-diphenylhomoallylamines. This reaction features a broad substrate scope with high yields and is conducted in an eco-friendly solvent, <i>i.e.</i> dimethyl carbonate."],"journal":["RSC advances"],"pagination":["18013-18017"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9064679"],"repository":["biostudies-literature"],"pubmed_title":["Lewis acidic FeCl<sub>3</sub> promoted 2-aza-Cope rearrangement to afford α-substituted homoallylamines in dimethyl carbonate."],"pmcid":["PMC9064679"],"pubmed_authors":["Maes BUW","Gadde K","Daelemans J","Abbaspour Tehrani K"],"additional_accession":[]},"is_claimable":false,"name":"Lewis acidic FeCl<sub>3</sub> promoted 2-aza-Cope rearrangement to afford α-substituted homoallylamines in dimethyl carbonate.","description":"The iron(iii)-catalyzed efficient strategy for the synthesis of α-substituted homoallylamines was accomplished <i>via</i> a cationic 2-aza-Cope rearrangement of aldimines, generated <i>in situ</i> by condensation of commercially available aldehydes and easily synthesizable 1,1-diphenylhomoallylamines. This reaction features a broad substrate scope with high yields and is conducted in an eco-friendly solvent, <i>i.e.</i> dimethyl carbonate.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Jun","modification":"2025-04-04T20:21:51.693Z","creation":"2025-04-04T20:21:51.693Z"},"accession":"S-EPMC9064679","cross_references":{"pubmed":["35520547"],"doi":["10.1039/c9ra03277k"]}}