{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Xie Z"],"funding":["Department of Agriculture of Guangdong Province","National Natural Science Foundation of China"],"pagination":["20314-20322"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9065458"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(35)"],"pubmed_abstract":["Hydrosilylation is one of the largest-scale applications for homogeneous catalysis and is widely used to enable the commercial manufacture of silicon products. In this paper, a bifunctional heterogeneous catalyst, Pt <sup><i>δ</i>+</sup>/AET-MIL-101 (AET = 2-aminoethanethiol) with a partially positively charged Pt <sup><i>δ</i>+</sup> electronic structure is reported, which was successfully prepared using post-synthesis modification with AET and a platinum precursor. The catalysts were characterized using X-ray diffraction (XRD), nitrogen (N<sub>2</sub>) adsorption-desorption, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) techniques which showed that the synergy of AET-MIL-101 provides a good dispersion of Pt <sup><i>δ</i>+</sup> in the channels, which can efficiently catalyze the hydrosilylation reaction with almost complete conversion and produce a unique adduct. In addition, the synthetic heterogeneous catalyst Pt <sup><i>δ</i>+</sup>/AET-MIL-101 achieves reasonable use of Pt in terms of number cycles and atomic utilization efficiency, indicating the potential to achieve a green hydrosilylation industry."],"journal":["RSC advances"],"pubmed_title":["Platinum on 2-aminoethanethiol functionalized MIL-101 as a catalyst for alkene hydrosilylation."],"pmcid":["PMC9065458"],"funding_grant_id":["KB1814325","21476272","KB1814324"],"pubmed_authors":["Hu W","Xie Z","Chen W","Shu X","Chen X","Zhou X"],"additional_accession":[]},"is_claimable":false,"name":"Platinum on 2-aminoethanethiol functionalized MIL-101 as a catalyst for alkene hydrosilylation.","description":"Hydrosilylation is one of the largest-scale applications for homogeneous catalysis and is widely used to enable the commercial manufacture of silicon products. In this paper, a bifunctional heterogeneous catalyst, Pt <sup><i>δ</i>+</sup>/AET-MIL-101 (AET = 2-aminoethanethiol) with a partially positively charged Pt <sup><i>δ</i>+</sup> electronic structure is reported, which was successfully prepared using post-synthesis modification with AET and a platinum precursor. The catalysts were characterized using X-ray diffraction (XRD), nitrogen (N<sub>2</sub>) adsorption-desorption, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) techniques which showed that the synergy of AET-MIL-101 provides a good dispersion of Pt <sup><i>δ</i>+</sup> in the channels, which can efficiently catalyze the hydrosilylation reaction with almost complete conversion and produce a unique adduct. In addition, the synthetic heterogeneous catalyst Pt <sup><i>δ</i>+</sup>/AET-MIL-101 achieves reasonable use of Pt in terms of number cycles and atomic utilization efficiency, indicating the potential to achieve a green hydrosilylation industry.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Jun","modification":"2025-04-22T07:45:59.528Z","creation":"2025-04-05T22:18:54.749Z"},"accession":"S-EPMC9065458","cross_references":{"pubmed":["35514732"],"doi":["10.1039/c9ra01408j"]}}