{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["78(Pt 5)"],"submitter":["Hirotsu M"],"pubmed_abstract":["The thiol-ate nickel complexes {2-[({2-[(2-amino-ethyl-κ<i>N</i>)(meth-yl)amino-κ<i>N</i>]eth-yl}imino-κ<i>N</i>)meth-yl]benzene-thiol-ato-κ<i>S</i>}nickel(II) chloride, [Ni(C<sub>12</sub>H<sub>18</sub>N<sub>3</sub>S)]Cl (<b>1</b>), and [2-({[2-(piperazin-1-yl-κ<sup>2</sup> <i>N</i> <sup>1</sup>,<i>N</i> <sup>4</sup>)eth-yl]imino-κ<i>N</i>}meth-yl)benzene-thiol-ato-κ<i>S</i>]nickel(II) hexa-fluoro-phosphate di-chloro-methane monosolvate, [Ni(C<sub>13</sub>H<sub>18</sub>N<sub>3</sub>S)]PF<sub>6</sub>·CH<sub>2</sub>Cl<sub>2</sub> (<b>2</b>), were synthesized by the reactions of 2-(<i>tert</i>-butyl-thio)-benzaldehyde, tri-amines, and nickel(II) salts. Both complexes have a nickel ion surrounded by an <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate ligand, forming a square-planar geometr"],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["500-505"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9069516"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structures and electrochemical properties of nickel(II) complexes with <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate Schiff base ligands."],"pmcid":["PMC9069516"],"pubmed_authors":["Hirotsu M","Kinoshita I","Sanou J","Nakae T","Matsunaga T"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structures and electrochemical properties of nickel(II) complexes with <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate Schiff base ligands.","description":"The thiol-ate nickel complexes {2-[({2-[(2-amino-ethyl-κ<i>N</i>)(meth-yl)amino-κ<i>N</i>]eth-yl}imino-κ<i>N</i>)meth-yl]benzene-thiol-ato-κ<i>S</i>}nickel(II) chloride, [Ni(C<sub>12</sub>H<sub>18</sub>N<sub>3</sub>S)]Cl (<b>1</b>), and [2-({[2-(piperazin-1-yl-κ<sup>2</sup> <i>N</i> <sup>1</sup>,<i>N</i> <sup>4</sup>)eth-yl]imino-κ<i>N</i>}meth-yl)benzene-thiol-ato-κ<i>S</i>]nickel(II) hexa-fluoro-phosphate di-chloro-methane monosolvate, [Ni(C<sub>13</sub>H<sub>18</sub>N<sub>3</sub>S)]PF<sub>6</sub>·CH<sub>2</sub>Cl<sub>2</sub> (<b>2</b>), were synthesized by the reactions of 2-(<i>tert</i>-butyl-thio)-benzaldehyde, tri-amines, and nickel(II) salts. Both complexes have a nickel ion surrounded by an <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate ligand, forming a square-planar geometr","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 May","modification":"2025-04-04T19:09:52.44Z","creation":"2024-11-08T19:29:33.763Z"},"accession":"S-EPMC9069516","cross_references":{"pubmed":["35547792"],"doi":["10.1107/S2056989022003954"]}}