biostudies-literatureUnknown78(Pt 5)Hirotsu MThe thiol-ate nickel complexes {2-[({2-[(2-amino-ethyl-κ<i>N</i>)(meth-yl)amino-κ<i>N</i>]eth-yl}imino-κ<i>N</i>)meth-yl]benzene-thiol-ato-κ<i>S</i>}nickel(II) chloride, [Ni(C₁₂H₁₈N₃S)]Cl (<b>1</b>), and [2-({[2-(piperazin-1-yl-κ² <i>N</i> ¹,<i>N</i> ⁴)eth-yl]imino-κ<i>N</i>}meth-yl)benzene-thiol-ato-κ<i>S</i>]nickel(II) hexa-fluoro-phosphate di-chloro-methane monosolvate, [Ni(C₁₃H₁₈N₃S)]PF₆·CH₂Cl₂ (<b>2</b>), were synthesized by the reactions of 2-(<i>tert</i>-butyl-thio)-benzaldehyde, tri-amines, and nickel(II) salts. Both complexes have a nickel ion surrounded by an <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate ligand, forming a square-planar geometrActa crystallographica. Section E, Crystallographic communications500-505https://www.ebi.ac.uk/biostudies/studies/S-EPMC9069516biostudies-literatureCrystal structures and electrochemical properties of nickel(II) complexes with <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate Schiff base ligands.PMC9069516Hirotsu MKinoshita ISanou JNakae TMatsunaga TfalseCrystal structures and electrochemical properties of nickel(II) complexes with <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate Schiff base ligands.The thiol-ate nickel complexes {2-[({2-[(2-amino-ethyl-κ<i>N</i>)(meth-yl)amino-κ<i>N</i>]eth-yl}imino-κ<i>N</i>)meth-yl]benzene-thiol-ato-κ<i>S</i>}nickel(II) chloride, [Ni(C₁₂H₁₈N₃S)]Cl (<b>1</b>), and [2-({[2-(piperazin-1-yl-κ² <i>N</i> ¹,<i>N</i> ⁴)eth-yl]imino-κ<i>N</i>}meth-yl)benzene-thiol-ato-κ<i>S</i>]nickel(II) hexa-fluoro-phosphate di-chloro-methane monosolvate, [Ni(C₁₃H₁₈N₃S)]PF₆·CH₂Cl₂ (<b>2</b>), were synthesized by the reactions of 2-(<i>tert</i>-butyl-thio)-benzaldehyde, tri-amines, and nickel(II) salts. Both complexes have a nickel ion surrounded by an <i>N</i>,<i>N</i>',<i>N</i>'',<i>S</i>-tetra-dentate ligand, forming a square-planar geometr2022-01-01T00:00:00Z2022 May2025-04-04T19:09:52.44Z2024-11-08T19:29:33.763ZS-EPMC90695163554779210.1107/S2056989022003954