biostudies-literatureUnknown9(42)Xia KCompared with static hydrothermal synthesis, the crystallization rate of an AlPO₄-5 molecular sieve has been accelerated distinctly by a rotating hydrothermal synthesis route with obviously decreased crystal particle size, which is assumed to be ascribed to the increased nucleation centers, accelerated crystal nucleation and growth processes; five-coordinated Al is dominant in the initial reaction gel, and the assembly from amorphous Al species to long-range ordered crystals is mainly contributed by the conversion from five-coordinated Al to four-coordinated Al.RSC advances24171-24174https://www.ebi.ac.uk/biostudies/studies/S-EPMC9069785biostudies-literatureHighly efficient crystallization of AlPO₄-5 accelerated by a rotating hydrothermal synthesis route.PMC9069785Xia KHe ZLu XXia QZhou DfalseHighly efficient crystallization of AlPO₄-5 accelerated by a rotating hydrothermal synthesis route.Compared with static hydrothermal synthesis, the crystallization rate of an AlPO₄-5 molecular sieve has been accelerated distinctly by a rotating hydrothermal synthesis route with obviously decreased crystal particle size, which is assumed to be ascribed to the increased nucleation centers, accelerated crystal nucleation and growth processes; five-coordinated Al is dominant in the initial reaction gel, and the assembly from amorphous Al species to long-range ordered crystals is mainly contributed by the conversion from five-coordinated Al to four-coordinated Al.2019-01-01T00:00:00Z2019 Aug2025-04-04T23:34:14.553Z2025-04-04T23:34:14.553ZS-EPMC90697853552790810.1039/c9ra04842a