{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["9(65)"],"submitter":["Yang EC"],"pubmed_abstract":["This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn<sub>12</sub> metal cluster, [Mn<sub>12</sub>O<sub>7</sub>(OH)<sub>2</sub>(OMe)<sub>2</sub>(dmhmp)<sub>4</sub>(O<sub>2</sub>CPh)<sub>11</sub>(H<sub>2</sub>O)] (6) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound (6) was obtained by reacting MnCl<sub>2</sub>·4H<sub>2</sub>O with dmhmpH in the presence of benzoic salt and Et<sub>3</sub>N. The resulting crystalline material is assigned to the triclinic space group <i>P</i>1̄. Although compound (6) displays ferromagnetic and antiferromagnetic competition behavior, this does not prevent the molecule from functioning as a single-molecule magnet (SMM). The SMM behavior is evidenced by observing frequency dependent out-of-phase ac "],"journal":["RSC advances"],"pagination":["37740-37746"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9075757"],"repository":["biostudies-literature"],"pubmed_title":["A new member of a class of rod-like Mn<sub>12</sub> single molecule magnets using 2-(pyridine-2-ly)propan-2-ol."],"pmcid":["PMC9075757"],"pubmed_authors":["Yang EC","Hong LX","Niekamp L","Huang SY","Lee GH","Damjanovic M","Wernsdorfer W"],"additional_accession":[]},"is_claimable":false,"name":"A new member of a class of rod-like Mn<sub>12</sub> single molecule magnets using 2-(pyridine-2-ly)propan-2-ol.","description":"This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn<sub>12</sub> metal cluster, [Mn<sub>12</sub>O<sub>7</sub>(OH)<sub>2</sub>(OMe)<sub>2</sub>(dmhmp)<sub>4</sub>(O<sub>2</sub>CPh)<sub>11</sub>(H<sub>2</sub>O)] (6) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound (6) was obtained by reacting MnCl<sub>2</sub>·4H<sub>2</sub>O with dmhmpH in the presence of benzoic salt and Et<sub>3</sub>N. The resulting crystalline material is assigned to the triclinic space group <i>P</i>1̄. Although compound (6) displays ferromagnetic and antiferromagnetic competition behavior, this does not prevent the molecule from functioning as a single-molecule magnet (SMM). The SMM behavior is evidenced by observing frequency dependent out-of-phase ac ","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Nov","modification":"2025-05-18T12:07:36.429Z","creation":"2025-04-19T07:27:24.073Z"},"accession":"S-EPMC9075757","cross_references":{"pubmed":["35541795"],"doi":["10.1039/c9ra06280g"]}}