{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Hu J"],"funding":["Natural Science Foundation of Guangxi Province","National Natural Science Foundation of China"],"pagination":["710-716"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9076843"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["8(2)"],"pubmed_abstract":["A novel thermally stable and aggregation-induced emission (AIE) active compound, 2,2'-(([1,1'-biphenyl]-4,4'-diylbis(phenylazanediyl))bis(4,1-phenylene))bis(3,3-diphenylacrylonitrile) (BP2TPAN) was synthesized through a C-N coupling reaction between 2-(4-bromophenyl)-3,3-diphenylacrylonitrile (Br-TPAN) and <i>N</i>,<i>N</i>'-diphenyl-1,4-phenylenediamine, under mild conditions using Pd(OAc)<sub>2</sub> and P(<i>t</i>-Bu)<sub>3</sub> as a catalyst. The BP2TPAN was characterized by nuclear magnetic resonance spectroscopy, high resolution mass spectrometry and elemental analysis. The thermal analysis showed that the glass transition and decomposition temperatures (5% weight loss) are 96 and 414 °C, respectively. The fluorescent emission peaks changes at 540 and 580 nm upon grinding were attri"],"journal":["RSC advances"],"pubmed_title":["A novel triphenylacrylonitrile based AIEgen for high contrast mechanchromism and bicolor electroluminescence."],"pmcid":["PMC9076843"],"funding_grant_id":["2016GXNSFBA380064","51603050"],"pubmed_authors":["Liu Y","Yuan WZ","Hu J","He G","Wei C","Jiang B","Gong Y"],"additional_accession":[]},"is_claimable":false,"name":"A novel triphenylacrylonitrile based AIEgen for high contrast mechanchromism and bicolor electroluminescence.","description":"A novel thermally stable and aggregation-induced emission (AIE) active compound, 2,2'-(([1,1'-biphenyl]-4,4'-diylbis(phenylazanediyl))bis(4,1-phenylene))bis(3,3-diphenylacrylonitrile) (BP2TPAN) was synthesized through a C-N coupling reaction between 2-(4-bromophenyl)-3,3-diphenylacrylonitrile (Br-TPAN) and <i>N</i>,<i>N</i>'-diphenyl-1,4-phenylenediamine, under mild conditions using Pd(OAc)<sub>2</sub> and P(<i>t</i>-Bu)<sub>3</sub> as a catalyst. The BP2TPAN was characterized by nuclear magnetic resonance spectroscopy, high resolution mass spectrometry and elemental analysis. The thermal analysis showed that the glass transition and decomposition temperatures (5% weight loss) are 96 and 414 °C, respectively. The fluorescent emission peaks changes at 540 and 580 nm upon grinding were attri","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Jan","modification":"2025-04-19T09:21:24.661Z","creation":"2025-02-19T03:25:51.228Z"},"accession":"S-EPMC9076843","cross_references":{"pubmed":["35538941"],"doi":["10.1039/c7ra10174k"]}}