{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Liao Y"],"funding":["Natural Science Foundation of Shanxi Province"],"pagination":["785-791"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9076883"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["8(2)"],"pubmed_abstract":["The Ca-Al and Ca-Al-X (X = F-, Cl- and Br-) catalysts were prepared via thermal decomposition of Ca-Al layered double hydroxides (LDHs), and tested for methanolysis of propylene carbonate (PC) to produce dimethyl carbonate (DMC). The catalytic performance of these catalysts increased in the order of Ca-Al-Br- < Ca-Al < Ca-Al-Cl- < Ca-Al-F-, which was consistent with the strong basicity of these materials. The recyclability test results showed that the addition of Al and halogens (F-, Cl- and Br-) not only stabilized the CaO but also improved the recyclability of the catalysts. Particularly, the Ca-Al-F- catalyst exerted the highest stability after 10 recycles. These catalyst"],"journal":["RSC advances"],"pubmed_title":["Solid base catalysts derived from Ca-Al-X (X = F-, Cl- and Br-) layered double hydroxides for methanolysis of propylene carbonate."],"pmcid":["PMC9076883"],"funding_grant_id":["201601D102006"],"pubmed_authors":["Liao Y","Zhao N","Li F","Pu Y","Wang F","Xiao F","Dai X"],"additional_accession":[]},"is_claimable":false,"name":"Solid base catalysts derived from Ca-Al-X (X = F-, Cl- and Br-) layered double hydroxides for methanolysis of propylene carbonate.","description":"The Ca-Al and Ca-Al-X (X = F-, Cl- and Br-) catalysts were prepared via thermal decomposition of Ca-Al layered double hydroxides (LDHs), and tested for methanolysis of propylene carbonate (PC) to produce dimethyl carbonate (DMC). The catalytic performance of these catalysts increased in the order of Ca-Al-Br- < Ca-Al < Ca-Al-Cl- < Ca-Al-F-, which was consistent with the strong basicity of these materials. The recyclability test results showed that the addition of Al and halogens (F-, Cl- and Br-) not only stabilized the CaO but also improved the recyclability of the catalysts. Particularly, the Ca-Al-F- catalyst exerted the highest stability after 10 recycles. These catalyst","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Jan","modification":"2025-04-04T23:16:22.541Z","creation":"2025-02-19T03:24:50.793Z"},"accession":"S-EPMC9076883","cross_references":{"pubmed":["35538981"],"doi":["10.1039/c7ra10832j"]}}