biostudies-literatureUnknown8(15)Gelat FA UV-mediated hydrophosphinylation of unactivated alkenes with <i>H</i>-phosphinates and hypophosphorous acid under radical free conditions is presented. The reaction affords selectively a large number of structurally diverse organophosphorous compounds in moderate to good yields under mild reaction conditions in the presence of an organic sensitizer as catalyst irradiated by UV-A LEDs. Furthermore, the high yielding hydrophosphinylation in continuous flow is disclosed.RSC advances8385-8392https://www.ebi.ac.uk/biostudies/studies/S-EPMC9078595biostudies-literatureUV-mediated hydrophosphinylation of unactivated alkenes with phosphinates under batch and flow conditions.PMC9078595Mazzad APenverne CGelat FRoger MRolando CChausset-Boissarie LfalseUV-mediated hydrophosphinylation of unactivated alkenes with phosphinates under batch and flow conditions.A UV-mediated hydrophosphinylation of unactivated alkenes with <i>H</i>-phosphinates and hypophosphorous acid under radical free conditions is presented. The reaction affords selectively a large number of structurally diverse organophosphorous compounds in moderate to good yields under mild reaction conditions in the presence of an organic sensitizer as catalyst irradiated by UV-A LEDs. Furthermore, the high yielding hydrophosphinylation in continuous flow is disclosed.2018-01-01T00:00:00Z2018 Feb2025-04-04T23:16:51.395Z2025-02-19T03:24:13.423ZS-EPMC90785953554203910.1039/c7ra12977g