biostudies-literatureUnknown8(26)Allu ARUnderstanding the conductivity variations induced by compositional changes in sodium super ionic conducting (NASICON) glass materials is highly relevant for applications such as solid electrolytes for sodium (Na) ion batteries. In the research reported in this paper, NASICON-based NCAP glass (Na_2.8Ca_0.1Al₂P₃O₁₂) was selected as the parent glass. The present study demonstrates the changes in the Na⁺ ion conductivity of NCAP bulk glass with the substitution of boron (NCABP: Na_2.8Ca_0.1Al₂B_0.5P_2.7O₁₂) and gallium (NCAGP: Na_2.8Ca_0.1Al₂Ga_0.5P_2.7O₁₂) for phosphorus and the resulting structural variatioRSC advances14422-14433https://www.ebi.ac.uk/biostudies/studies/S-EPMC9079908biostudies-literatureStructural elucidation of NASICON (Na₃Al₂P₃O₁₂) based glass electrolyte materials: effective influence of boron and gallium.PMC9079908Ajithkumar TGAllu ARBalaji SIllath KBiswas KHareendran CAnnapurna KfalseStructural elucidation of NASICON (Na₃Al₂P₃O₁₂) based glass electrolyte materials: effective influence of boron and gallium.Understanding the conductivity variations induced by compositional changes in sodium super ionic conducting (NASICON) glass materials is highly relevant for applications such as solid electrolytes for sodium (Na) ion batteries. In the research reported in this paper, NASICON-based NCAP glass (Na_2.8Ca_0.1Al₂P₃O₁₂) was selected as the parent glass. The present study demonstrates the changes in the Na⁺ ion conductivity of NCAP bulk glass with the substitution of boron (NCABP: Na_2.8Ca_0.1Al₂B_0.5P_2.7O₁₂) and gallium (NCAGP: Na_2.8Ca_0.1Al₂Ga_0.5P_2.7O₁₂) for phosphorus and the resulting structural variatio2018-01-01T00:00:00Z2018 Apr2025-04-26T04:34:41.551Z2025-04-06T11:14:14.153ZS-EPMC90799083554073810.1039/c8ra01676c