{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["8(26)"],"submitter":["Ghasemi S"],"pubmed_abstract":["A thermo-responsive poly(<i>N</i>-isopropylacrylamide)-<i>block</i>-poly(ionic liquid) (PNIPAM-<i>b</i>-PIL) of pyridinium-type was prepared. Initially, controlled synthesis of PNIPAM was performed <i>via</i> RAFT method. Subsequently, PNIPAM as macromolecular chain transfer agent (macro-CTA) was used for fabrication of PNIPAM-<i>b</i>-PIL through reaction with a synthesized IL monomer <i>i.e.</i> 4-vinyl pyridinium propane sulfonate. The Pd catalyst was produced throughout palladium nanoparticles' anchoring into this block copolymer. The catalyst was characterized using ICP, FT-IR, NMR, UV-Vis, TGA, XRD, SEM and EDX techniques. The catalyst's TEM image proved nearly fine dispersion of PdNPs with negligible agglomeration. The catalyst was used in the production of a variety of substituted "],"journal":["RSC advances"],"pagination":["14570-14578"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9079935"],"repository":["biostudies-literature"],"pubmed_title":["Thermo-responsive poly(<i>N</i>-isopropylacrylamide)-<i>block</i>-poly(ionic liquid) of pyridinium sulfonate immobilized Pd nanoparticles in C-C coupling reactions."],"pmcid":["PMC9079935"],"pubmed_authors":["Ghasemi S","Harandi ZA"],"additional_accession":[]},"is_claimable":false,"name":"Thermo-responsive poly(<i>N</i>-isopropylacrylamide)-<i>block</i>-poly(ionic liquid) of pyridinium sulfonate immobilized Pd nanoparticles in C-C coupling reactions.","description":"A thermo-responsive poly(<i>N</i>-isopropylacrylamide)-<i>block</i>-poly(ionic liquid) (PNIPAM-<i>b</i>-PIL) of pyridinium-type was prepared. Initially, controlled synthesis of PNIPAM was performed <i>via</i> RAFT method. Subsequently, PNIPAM as macromolecular chain transfer agent (macro-CTA) was used for fabrication of PNIPAM-<i>b</i>-PIL through reaction with a synthesized IL monomer <i>i.e.</i> 4-vinyl pyridinium propane sulfonate. The Pd catalyst was produced throughout palladium nanoparticles' anchoring into this block copolymer. The catalyst was characterized using ICP, FT-IR, NMR, UV-Vis, TGA, XRD, SEM and EDX techniques. The catalyst's TEM image proved nearly fine dispersion of PdNPs with negligible agglomeration. The catalyst was used in the production of a variety of substituted ","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Apr","modification":"2025-04-04T23:17:18.043Z","creation":"2025-02-19T03:24:42.738Z"},"accession":"S-EPMC9079935","cross_references":{"pubmed":["35540787"],"doi":["10.1039/c8ra01303a"]}}