{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Getmanenko YA"],"funding":["Division of Chemistry","Office of Experimental Program to Stimulate Competitive Research","Division of Materials Research"],"pagination":["36223-36232"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9088712"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["8(63)"],"pubmed_abstract":["Here we present the synthesis and characterization of a hybrid vanadium-organic coordination polymer with robust magnetic order, a Curie temperature <i>T</i> <sub>C</sub> of ∼110 K, a coercive field of ∼5 Oe at 5 K, and a maximum mass magnetization of about half that of the benchmark ferrimagnetic vanadium(tetracyanoethylene)<sub>∼2</sub> (V·(TCNE)<sub>∼2</sub>). This material was prepared using a new tetracyano-substituted quinoidal organic small molecule 7 based on a tricyclic heterocycle 4-hexyl-4<i>H</i>-pyrrolo[2,3-<i>d</i>:5,4-<i>d</i>']bis(thiazole) (C<sub>6</sub>-PBTz). Single crystal X-ray diffraction of the 2,6-diiodo derivative of the parent C<sub>6</sub>-PBTz, showed a disordered hexyl chain and a nearly linear arrangement of the substituents in positions 2 and 6 of the tricycl"],"journal":["RSC advances"],"pubmed_title":["Magnetic ordering in a vanadium-organic coordination polymer using a pyrrolo[2,3-<i>d</i>:5,4-<i>d</i>']bis(thiazole)-based ligand."],"pmcid":["PMC9088712"],"funding_grant_id":["MRI Program CHE-1726652","IIA-1301346","1420451","1523611"],"pubmed_authors":["Risko C","Nesterov VN","Getmanenko YA","Mullins CS","Lake S","Johnston-Halperin E"],"additional_accession":[]},"is_claimable":false,"name":"Magnetic ordering in a vanadium-organic coordination polymer using a pyrrolo[2,3-<i>d</i>:5,4-<i>d</i>']bis(thiazole)-based ligand.","description":"Here we present the synthesis and characterization of a hybrid vanadium-organic coordination polymer with robust magnetic order, a Curie temperature <i>T</i> <sub>C</sub> of ∼110 K, a coercive field of ∼5 Oe at 5 K, and a maximum mass magnetization of about half that of the benchmark ferrimagnetic vanadium(tetracyanoethylene)<sub>∼2</sub> (V·(TCNE)<sub>∼2</sub>). This material was prepared using a new tetracyano-substituted quinoidal organic small molecule 7 based on a tricyclic heterocycle 4-hexyl-4<i>H</i>-pyrrolo[2,3-<i>d</i>:5,4-<i>d</i>']bis(thiazole) (C<sub>6</sub>-PBTz). Single crystal X-ray diffraction of the 2,6-diiodo derivative of the parent C<sub>6</sub>-PBTz, showed a disordered hexyl chain and a nearly linear arrangement of the substituents in positions 2 and 6 of the tricycl","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Oct","modification":"2025-04-04T21:32:35.872Z","creation":"2025-04-04T21:32:35.872Z"},"accession":"S-EPMC9088712","cross_references":{"pubmed":["35558484"],"doi":["10.1039/c8ra05697h"]}}