{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Liu L"],"funding":["High-tech Industrial Development Zone Science and Technology Huimin Plan of Weifang","Natural Science Foundation of Shandong Province","National Natural Science Foundation of China","Technology Research and Development Program of Weifang"],"pagination":["1484"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9105395"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["12(9)"],"pubmed_abstract":["Selective hydrogenation of 1,3-butadiene (BD) is regarded as the most promising route for removing BD from butene streams. Bimetallic Pd-Ni catalysts with changed Pd/Ni molar ratios and monometallic Pd catalysts were synthesized using two differently structured metal-organic framework supports: UiO-66 and UiO-66-NH<sub>2</sub>. The effects of the structure of support and the molar ratio of Pd/Ni on the catalytic property of selective BD hydrogenation were studied. The Pd-Ni bimetallic supported catalysts, PdNi/UiO-66 (1:1) and PdNi/UiO-66-NH<sub>2</sub> (1:1), exhibited fine catalytic property at low temperature. Compared with UiO-66, UiO-66-NH<sub>2</sub> with a certain number of alkaline sites could reduce the catalytic activity for the BD hydrogenation reaction. However, the alkaline en"],"journal":["Nanomaterials (Basel, Switzerland)"],"pubmed_title":["Comparative Study of Pd-Ni Bimetallic Catalysts Supported on UiO-66 and UiO-66-NH<sub>2</sub> in Selective 1,3-Butadiene Hydrogenation."],"pmcid":["PMC9105395"],"funding_grant_id":["2021GX007","2019KJHM18","ZR2017MB056","21802104"],"pubmed_authors":["Liu Y","Yu L","Liu Z","Liu L","Zhang J","Sun S","Xin C","Tai X","Zhou X"],"additional_accession":[]},"is_claimable":false,"name":"Comparative Study of Pd-Ni Bimetallic Catalysts Supported on UiO-66 and UiO-66-NH<sub>2</sub> in Selective 1,3-Butadiene Hydrogenation.","description":"Selective hydrogenation of 1,3-butadiene (BD) is regarded as the most promising route for removing BD from butene streams. Bimetallic Pd-Ni catalysts with changed Pd/Ni molar ratios and monometallic Pd catalysts were synthesized using two differently structured metal-organic framework supports: UiO-66 and UiO-66-NH<sub>2</sub>. The effects of the structure of support and the molar ratio of Pd/Ni on the catalytic property of selective BD hydrogenation were studied. The Pd-Ni bimetallic supported catalysts, PdNi/UiO-66 (1:1) and PdNi/UiO-66-NH<sub>2</sub> (1:1), exhibited fine catalytic property at low temperature. Compared with UiO-66, UiO-66-NH<sub>2</sub> with a certain number of alkaline sites could reduce the catalytic activity for the BD hydrogenation reaction. However, the alkaline en","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Apr","modification":"2025-04-22T19:48:30.964Z","creation":"2025-04-06T02:54:55.045Z"},"accession":"S-EPMC9105395","cross_references":{"pubmed":["35564194"],"doi":["10.3390/nano12091484"]}}