{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["2(5)"],"submitter":["Du J"],"pubmed_abstract":["Supported single-atom catalysts (SACs), with the extremely homogenized active sites could achieve high hydrogenation selectivity toward one of the functional groups coexisting in the reactant molecule. However, as to the target group, the control of selective recognition and activation by SACs still remains a challenge. Herein, the phase engineering of the support is adopted to control the chemo-recognition behavior of SACs in selective hydrogenation. Single-atom Ru on amorphous porous ultrathin TiO<sub>2</sub> nanosheets (Ru<sub>1</sub>/a-TiO<sub>2</sub>) is constructed, in which Ru is more positively charged than that in the crystalline counterpart (Ru<sub>1</sub>/c-TiO<sub>2</sub>). Moreover, in the nitro/vinyl selective hydrogenation process, Ru<sub>1</sub>/a-TiO<sub>2</sub> shows supe"],"journal":["JACS Au"],"pagination":["1078-1083"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9131367"],"repository":["biostudies-literature"],"pubmed_title":["Reversing the Catalytic Selectivity of Single-Atom Ru via Support Amorphization."],"pmcid":["PMC9131367"],"pubmed_authors":["Cui P","Jiang J","Zheng X","Huang Y","Hong X","Huang Z","Wu B","Han X","Du J","Wu G","Chen C","Wu Y"],"additional_accession":[]},"is_claimable":false,"name":"Reversing the Catalytic Selectivity of Single-Atom Ru via Support Amorphization.","description":"Supported single-atom catalysts (SACs), with the extremely homogenized active sites could achieve high hydrogenation selectivity toward one of the functional groups coexisting in the reactant molecule. However, as to the target group, the control of selective recognition and activation by SACs still remains a challenge. Herein, the phase engineering of the support is adopted to control the chemo-recognition behavior of SACs in selective hydrogenation. Single-atom Ru on amorphous porous ultrathin TiO<sub>2</sub> nanosheets (Ru<sub>1</sub>/a-TiO<sub>2</sub>) is constructed, in which Ru is more positively charged than that in the crystalline counterpart (Ru<sub>1</sub>/c-TiO<sub>2</sub>). Moreover, in the nitro/vinyl selective hydrogenation process, Ru<sub>1</sub>/a-TiO<sub>2</sub> shows supe","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 May","modification":"2025-04-04T12:57:01.494Z","creation":"2024-11-08T09:17:17.216Z"},"accession":"S-EPMC9131367","cross_references":{"pubmed":["35647593"],"doi":["10.1021/jacsau.2c00192"]}}