biostudies-literatureHuang JNatural Science Foundation of ChongqingChongqing Municipal Education Commission18085-18093https://www.ebi.ac.uk/biostudies/studies/S-EPMC9161382biostudies-literatureUnknown7(21)Gold nanoparticles (Au NPs) are installed in situ on the surfaces of graphitic carbon nitride (g-C₃N₄) based on supramolecular hydroxylatopillar[6]arene (P6). The Au NPs can be obtained via the redox reaction between HAuCl₄ and P6 without any NH₂-NH₂, NaBH₄, and other reductants, where AuCl₄ ^- is reduced to Au⁰ by the -OH groups in the presence of OH^-, and the -OH groups are oxidized into -COOH. First, P6 is loaded onto the surface of g-C₃N₄ via π-π interaction between P6 and g-C₃N₄, which offers a stabilized and reduced site for in situ anchoring of Au NPs. The hybrid nanomaterial Au-NPs@P6@g-C₃N₄ exhibits higher caACS omegaGreen Synthesis of Au-NPs on g-C₃N₄ Hybrid Nanomaterials Based on Supramolecular Pillar[6]arene and Its Applications for Catalysis.PMC9161382cstc2020jcyjmsxmX0341CXQT20026KJQN202101416Ran STan XLi CHuang JTao YMou TWu RfalseGreen Synthesis of Au-NPs on g-C₃N₄ Hybrid Nanomaterials Based on Supramolecular Pillar[6]arene and Its Applications for Catalysis.Gold nanoparticles (Au NPs) are installed in situ on the surfaces of graphitic carbon nitride (g-C₃N₄) based on supramolecular hydroxylatopillar[6]arene (P6). The Au NPs can be obtained via the redox reaction between HAuCl₄ and P6 without any NH₂-NH₂, NaBH₄, and other reductants, where AuCl₄ ^- is reduced to Au⁰ by the -OH groups in the presence of OH^-, and the -OH groups are oxidized into -COOH. First, P6 is loaded onto the surface of g-C₃N₄ via π-π interaction between P6 and g-C₃N₄, which offers a stabilized and reduced site for in situ anchoring of Au NPs. The hybrid nanomaterial Au-NPs@P6@g-C₃N₄ exhibits higher ca2022-01-01T00:00:00Z2022 May2025-04-04T19:06:25.723Z2024-11-13T05:14:24.971ZS-EPMC91613823566460310.1021/acsomega.2c01603