{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Shun K"],"funding":["Japan Society for the Promotion of Science"],"pagination":["8137-8147"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9278487"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["13(27)"],"pubmed_abstract":["Hydrogen spillover, the migration of dissociated hydrogen atoms from noble metals to their support materials, is a ubiquitous phenomenon and is widely utilized in heterogeneous catalysis and hydrogen storage materials. However, in-depth understanding of the migration of spilled hydrogen over different types of supports is still lacking. Herein, hydrogen spillover in typical reducible metal oxides, such as TiO<sub>2</sub>, CeO<sub>2</sub>, and WO<sub>3</sub>, was elucidated by combining systematic characterization methods involving various <i>in situ</i> techniques, kinetic analysis, and density functional theory calculations. TiO<sub>2</sub> and CeO<sub>2</sub> were proven to be promising platforms for the synthesis of non-equilibrium RuNi binary solid solution alloy nanoparticles displayi"],"journal":["Chemical science"],"pubmed_title":["Revealing hydrogen spillover pathways in reducible metal oxides."],"pmcid":["PMC9278487"],"funding_grant_id":["21B206","JPMXP0112101003"],"pubmed_authors":["Yamashita H","Mori K","Masuda S","Hashimoto N","Shun K","Kobayashi H","Hinuma Y"],"additional_accession":[]},"is_claimable":false,"name":"Revealing hydrogen spillover pathways in reducible metal oxides.","description":"Hydrogen spillover, the migration of dissociated hydrogen atoms from noble metals to their support materials, is a ubiquitous phenomenon and is widely utilized in heterogeneous catalysis and hydrogen storage materials. However, in-depth understanding of the migration of spilled hydrogen over different types of supports is still lacking. Herein, hydrogen spillover in typical reducible metal oxides, such as TiO<sub>2</sub>, CeO<sub>2</sub>, and WO<sub>3</sub>, was elucidated by combining systematic characterization methods involving various <i>in situ</i> techniques, kinetic analysis, and density functional theory calculations. TiO<sub>2</sub> and CeO<sub>2</sub> were proven to be promising platforms for the synthesis of non-equilibrium RuNi binary solid solution alloy nanoparticles displayi","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Jul","modification":"2025-04-26T16:19:46.114Z","creation":"2025-04-06T15:08:46.73Z"},"accession":"S-EPMC9278487","cross_references":{"pubmed":["35919430"],"doi":["10.1039/d2sc00871h"]}}