{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Lorber K"],"funding":["H2020 European Institute of Innovation and Technology","Deutsches Elektronen-Synchrotron","Javna Agencija za Raziskovalno Dejavnost RS","Elettra-Sincrotrone Trieste"],"pagination":["31862-31878"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9305712"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["14(28)"],"pubmed_abstract":["Dry reforming of methane (DRM) is a promising way to convert methane and carbon dioxide into H<sub>2</sub> and CO (syngas). CeO<sub>2</sub> nanorods, nanocubes, and nanospheres were decorated with 1-4 wt % Ni. The materials were structurally characterized using TEM and <i>in situ</i> XANES/EXAFS. The CO<sub>2</sub> activation was analyzed by DFT and temperature-programmed techniques combined with MS-DRIFTS. Synthesized CeO<sub>2</sub> morphologies expose {111} and {100} terminating facets, varying the strength of the CO<sub>2</sub> interaction and redox properties, which influence the CO<sub>2</sub> activation. Temperature-programmed CO<sub>2</sub> DRIFTS analysis revealed that under hydrogen-lean conditions mono- and bidentate carbonates are hydrogenated to formate intermediates, which de"],"journal":["ACS applied materials & interfaces"],"pubmed_title":["CO<sub>2</sub> Activation over Nanoshaped CeO<sub>2</sub> Decorated with Nickel for Low-Temperature Methane Dry Reforming."],"pmcid":["PMC9305712"],"funding_grant_id":["730872","P2-0150","823717","I-20180898 EC","20185092","I0-0039","P2-0152","J7-7294","P1-0112","J2-1726"],"pubmed_authors":["Lorber K","Terzan J","Djinovic P","Zavasnik J","Likozar B","Arcon I","Hus M"],"additional_accession":[]},"is_claimable":false,"name":"CO<sub>2</sub> Activation over Nanoshaped CeO<sub>2</sub> Decorated with Nickel for Low-Temperature Methane Dry Reforming.","description":"Dry reforming of methane (DRM) is a promising way to convert methane and carbon dioxide into H<sub>2</sub> and CO (syngas). CeO<sub>2</sub> nanorods, nanocubes, and nanospheres were decorated with 1-4 wt % Ni. The materials were structurally characterized using TEM and <i>in situ</i> XANES/EXAFS. The CO<sub>2</sub> activation was analyzed by DFT and temperature-programmed techniques combined with MS-DRIFTS. Synthesized CeO<sub>2</sub> morphologies expose {111} and {100} terminating facets, varying the strength of the CO<sub>2</sub> interaction and redox properties, which influence the CO<sub>2</sub> activation. Temperature-programmed CO<sub>2</sub> DRIFTS analysis revealed that under hydrogen-lean conditions mono- and bidentate carbonates are hydrogenated to formate intermediates, which de","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Jul","modification":"2025-04-25T21:48:27.636Z","creation":"2025-02-19T03:52:47.678Z"},"accession":"S-EPMC9305712","cross_references":{"pubmed":["35801412"],"doi":["10.1021/acsami.2c05221"]}}