{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Girel S"],"funding":["German Research Foundation","German Research Foundation Priority Program"],"pagination":["4786"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9330447"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["27(15)"],"pubmed_abstract":["Incubation of <i>Aminobacter aminovorans</i>, <i>Paenibacillus polymyxa</i>, and <i>Arthrobacter</i> MPI764 with the microbial 2-benzoxazolinone (BOA)-degradation-product <i>2</i>-acetamido-phenol, produced from 2-aminophenol, led to the recently identified <i>N</i>-(2-hydroxy-5-nitrophenyl) acetamide, to the hitherto unknown <i>N-</i>(2-hydroxy-5-nitrosophenyl)acetamide, and to <i>N-</i>(2-hydroxy-3-nitrophenyl)acetamide. As an alternative to the formation of phenoxazinone derived from aminophenol, dimers- and trimers-transformation products have been found. Identification of the compounds was carried out by LC/HRMS and MS/MS and, for the new structure <i>N-</i>(2-hydroxy-5-nitrosophenyl)acetamide, additionally by 1D- and 2D-NMR. Incubation of microorganisms, such as the soil bacteria <i>"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Bioactive Nitrosylated and Nitrated <i>N</i>-(2-hydroxyphenyl)acetamides and Derived Oligomers: An Alternative Pathway to 2-Amidophenol-Derived Phytotoxic Metabolites."],"pmcid":["PMC9330447"],"funding_grant_id":["DECRyPT","Do520/17","SPP 2125","Priority Program SPP 2125, DECRyPT, Do520/17-1)"],"pubmed_authors":["Schutz V","Bigler L","Girel S","Dormann P","Schulz M"],"additional_accession":[]},"is_claimable":false,"name":"Bioactive Nitrosylated and Nitrated <i>N</i>-(2-hydroxyphenyl)acetamides and Derived Oligomers: An Alternative Pathway to 2-Amidophenol-Derived Phytotoxic Metabolites.","description":"Incubation of <i>Aminobacter aminovorans</i>, <i>Paenibacillus polymyxa</i>, and <i>Arthrobacter</i> MPI764 with the microbial 2-benzoxazolinone (BOA)-degradation-product <i>2</i>-acetamido-phenol, produced from 2-aminophenol, led to the recently identified <i>N</i>-(2-hydroxy-5-nitrophenyl) acetamide, to the hitherto unknown <i>N-</i>(2-hydroxy-5-nitrosophenyl)acetamide, and to <i>N-</i>(2-hydroxy-3-nitrophenyl)acetamide. As an alternative to the formation of phenoxazinone derived from aminophenol, dimers- and trimers-transformation products have been found. Identification of the compounds was carried out by LC/HRMS and MS/MS and, for the new structure <i>N-</i>(2-hydroxy-5-nitrosophenyl)acetamide, additionally by 1D- and 2D-NMR. Incubation of microorganisms, such as the soil bacteria <i>","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Jul","modification":"2026-04-08T10:48:55.028Z","creation":"2024-11-09T19:32:49.31Z"},"accession":"S-EPMC9330447","cross_references":{"pubmed":["35897961"],"doi":["10.3390/molecules27154786"]}}