{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Liu Z"],"funding":["National Natural Science Foundation of China"],"pagination":["4716"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9372153"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["13(1)"],"pubmed_abstract":["Producing monomeric phenols from lignin biopolymer depolymerization in a detachable and efficient manner comes under the spotlight on the fullest utilization of sustainable lignocellulosic biomass. Here, we report a low-loaded and highly dispersed Ru anchored on a chitosan-derived N-doped carbon catalyst (RuN/ZnO/C), which exhibits outstanding performance in the reductive catalytic fractionation of lignocellulose. Nearly theoretical maximum yields of phenolic monomers from lignin are achieved, corresponding to TON as 431 mol<sub>phenols</sub> mol<sub>Ru</sub><sup>-1</sup>, 20 times higher than that from commercial Ru/C catalyst; high selectivity toward propyl end-chained guaiacol and syringol allow them to be readily purified. The RCF leave high retention of (hemi)cellulose amenable to enz"],"journal":["Nature communications"],"pubmed_title":["Rational highly dispersed ruthenium for reductive catalytic fractionation of lignocellulose."],"pmcid":["PMC9372153"],"funding_grant_id":["31971607"],"pubmed_authors":["Fang Y","Li H","Liu Z","Guo X","Wang S","Gao X","Song G"],"additional_accession":[]},"is_claimable":false,"name":"Rational highly dispersed ruthenium for reductive catalytic fractionation of lignocellulose.","description":"Producing monomeric phenols from lignin biopolymer depolymerization in a detachable and efficient manner comes under the spotlight on the fullest utilization of sustainable lignocellulosic biomass. Here, we report a low-loaded and highly dispersed Ru anchored on a chitosan-derived N-doped carbon catalyst (RuN/ZnO/C), which exhibits outstanding performance in the reductive catalytic fractionation of lignocellulose. Nearly theoretical maximum yields of phenolic monomers from lignin are achieved, corresponding to TON as 431 mol<sub>phenols</sub> mol<sub>Ru</sub><sup>-1</sup>, 20 times higher than that from commercial Ru/C catalyst; high selectivity toward propyl end-chained guaiacol and syringol allow them to be readily purified. The RCF leave high retention of (hemi)cellulose amenable to enz","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Aug","modification":"2025-04-27T03:23:35.14Z","creation":"2025-04-06T18:46:44.798Z"},"accession":"S-EPMC9372153","cross_references":{"pubmed":["35953497"],"doi":["10.1038/s41467-022-32451-5"]}}