{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Zhao M"],"funding":["the Scientific Research and Innovation Fund Project of Shandong Energy Research Institute","Guangxi Science and Technology Project","Linyi University","Taishan Scholars Program of Shandong Province"],"pagination":["3612"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9459928"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["14(17)"],"pubmed_abstract":["Iron complexes of the types [Fe(HL)<sub>2</sub>Cl<sub>2</sub>] (<b>Fe1</b>: HL<sup>1</sup> = pyridine-2-aldoxime; <b>Fe2</b>: HL<sup>2</sup> = 6-methylpyridine-2-aldoxime; <b>Fe3</b>: HL<sup>3</sup> = phenyl-2-pyridylketoxime; <b>Fe4</b>: HL<sup>4</sup> = picolinaldehyde O-methyl oxime) were prepared and characterized by elemental analysis and IR spectroscopy. The crystal structure of <b>Fe2</b>, determined by single-crystal X-ray diffraction, featured a distorted octahedral coordination of the iron center binding with two ligands of HL<sup>2</sup>. The X-ray structure and infrared spectral data indicated that pyridine-oxime ligands act as unionized bidentate ligand by coordinating with N<sub>pyridine</sub> and N<sub>oxime</sub>. The catalytic performance for isoprene polymerization, catal"],"journal":["Polymers"],"pubmed_title":["Synthesis, Characterization and Catalytic Property Studies for Isoprene Polymerization of Iron Complexes Bearing Unionized Pyridine-Oxime Ligands."],"pmcid":["PMC9459928"],"funding_grant_id":["SEI S202101","LYDX2020BS012","tsqn201812112","Grant No. AB21196038；Talent No. AD21238015"],"pubmed_authors":["Zhao M","Wang Q","Zhang X","Ma Y","Zhu G","Wang L"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis, Characterization and Catalytic Property Studies for Isoprene Polymerization of Iron Complexes Bearing Unionized Pyridine-Oxime Ligands.","description":"Iron complexes of the types [Fe(HL)<sub>2</sub>Cl<sub>2</sub>] (<b>Fe1</b>: HL<sup>1</sup> = pyridine-2-aldoxime; <b>Fe2</b>: HL<sup>2</sup> = 6-methylpyridine-2-aldoxime; <b>Fe3</b>: HL<sup>3</sup> = phenyl-2-pyridylketoxime; <b>Fe4</b>: HL<sup>4</sup> = picolinaldehyde O-methyl oxime) were prepared and characterized by elemental analysis and IR spectroscopy. The crystal structure of <b>Fe2</b>, determined by single-crystal X-ray diffraction, featured a distorted octahedral coordination of the iron center binding with two ligands of HL<sup>2</sup>. The X-ray structure and infrared spectral data indicated that pyridine-oxime ligands act as unionized bidentate ligand by coordinating with N<sub>pyridine</sub> and N<sub>oxime</sub>. The catalytic performance for isoprene polymerization, catal","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Sep","modification":"2025-04-19T07:09:08.014Z","creation":"2025-04-19T07:09:08.014Z"},"accession":"S-EPMC9459928","cross_references":{"pubmed":["36080685"],"doi":["10.3390/polym14173612"]}}