biostudies-literatureUnknown12(44)Shi HFluorescent carbon dots (CDs) were synthesized by a one-step hydrothermal treatment of wild jujube and dl-tryptophan. The structure and properties of the CDs were confirmed by transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible absorption spectroscopy, fluorescence spectroscopy and so on. The as-prepared CDs exhibit excellent excitation-independent but pH-dependent (4.0-12.0) fluorescent features and emit blue strong fluorescence under 365 nm light. Hg²⁺ can decrease the fluorescence intensity of the CDs through static quenching, while the addition of oxalic acid (OA) recovers it owing to the coordination binding between oxalic acid and Hg²⁺. Based on this, the as-prepared CDs were used as a new "off-on" fluorescent probe for highly sensitive determination of oxalic acid with a wide linear detection range of 0.1-20 mg L^-1 and a low detection limit of 0.057 mg L^-1. Moreover, the fluorescent probe was successfully applied to detect oxalic acid in tomato and cherry tomato samples with satisfactory results.RSC advances28545-28552https://www.ebi.ac.uk/biostudies/studies/S-EPMC9535697biostudies-literatureWild jujube-based fluorescent carbon dots for highly sensitive determination of oxalic acid.PMC9535697Li XLi YFeng SShi HfalseWild jujube-based fluorescent carbon dots for highly sensitive determination of oxalic acid.Fluorescent carbon dots (CDs) were synthesized by a one-step hydrothermal treatment of wild jujube and dl-tryptophan. The structure and properties of the CDs were confirmed by transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible absorption spectroscopy, fluorescence spectroscopy and so on. The as-prepared CDs exhibit excellent excitation-independent but pH-dependent (4.0-12.0) fluorescent features and emit blue strong fluorescence under 365 nm light. Hg²⁺ can decrease the fluorescence intensity of the CDs through static quenching, while the addition of oxalic acid (OA) recovers it owing to the coordination binding between oxalic acid and Hg²⁺. Based on this, the as-prepared CDs were used as a new "off-on" fluorescent probe for highly sensitive determination of oxalic acid with a wide linear detection range of 0.1-20 mg L^-1 and a low detection limit of 0.057 mg L^-1. Moreover, the fluorescent probe was successfully applied to detect oxalic acid in tomato and cherry tomato samples with satisfactory results.2022-01-01T00:00:00Z2022 Oct2025-04-05T13:27:30.244Z2025-04-05T13:27:30.244ZS-EPMC95356973632053910.1039/d2ra03780g