{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["DiNardi RG"],"funding":["Australian Research Council"],"pagination":["e202205701"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9541570"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(38)"],"pubmed_abstract":["A photoswitchable ligand based on azobenzene is self-assembled with palladium(II) ions to form a [Pd<sub>2</sub> (E-L)<sub>4</sub> ]<sup>4+</sup> cage. Irradiation with 470 nm light results in the near-quantitative switching to a monomeric species [Pd(Z-L)<sub>2</sub> ]<sup>2+</sup> , which can be reversed by irradiation with 405 nm light, or heat. The photoswitching selectivity towards the metastable isomer is significantly improved upon self-assembly, and the thermal half-life is extended from 40 days to 850 days, a promising approach for tuning photoswitching properties."],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Visible-Light-Responsive Self-Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination."],"pmcid":["PMC9541570"],"funding_grant_id":["FT170100094"],"pubmed_authors":["DiNardi RG","Tajik M","Donald WA","Tian R","Beves JE","Douglas AO","Price JR"],"additional_accession":[]},"is_claimable":false,"name":"Visible-Light-Responsive Self-Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination.","description":"A photoswitchable ligand based on azobenzene is self-assembled with palladium(II) ions to form a [Pd<sub>2</sub> (E-L)<sub>4</sub> ]<sup>4+</sup> cage. Irradiation with 470 nm light results in the near-quantitative switching to a monomeric species [Pd(Z-L)<sub>2</sub> ]<sup>2+</sup> , which can be reversed by irradiation with 405 nm light, or heat. The photoswitching selectivity towards the metastable isomer is significantly improved upon self-assembly, and the thermal half-life is extended from 40 days to 850 days, a promising approach for tuning photoswitching properties.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Sep","modification":"2025-04-19T04:47:08.13Z","creation":"2025-04-19T04:47:08.13Z"},"accession":"S-EPMC9541570","cross_references":{"pubmed":["35972841"],"doi":["10.1002/anie.202205701"]}}