{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Widemann M"],"funding":["Deutsche Forschungsgemeinschaft"],"pagination":["e202201032"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9541956"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["28(45)"],"pubmed_abstract":["Following the alkane-elimination route, the reaction between tetravalent aryl tintrihydride Ar*SnH<sub>3</sub> and trivalent rare-earth-metallocene alkyls [Cp*<sub>2</sub> Ln(CH{SiMe<sub>3</sub> }<sub>2</sub> )] gave complexes [Cp*<sub>2</sub> Ln(μ-H)<sub>2</sub> SnAr*] implementing a low-valent tin hydride (Ln=Y, Lu; Ar*=2,6-Trip<sub>2</sub> C<sub>6</sub> H<sub>3</sub> , Trip=2,4,6-triisopropylphenyl). The homologous complexes of germanium and lead, [Cp*<sub>2</sub> Ln(μ-H)<sub>2</sub> EAr*] (E = Ge, Pb), were accessed via addition of low-valent [(Ar*EH)<sub>2</sub> ] to the rare-earth-metal hydrides [(Cp*<sub>2</sub> LnH)<sub>2</sub> ]. The lead compounds [Cp*<sub>2</sub> Ln(μ-H)<sub>2</sub> PbAr*] exhibit H/D exchange in reactions with deuterated solvents or dihydrogen."],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pubmed_title":["Molecular Ln(III)-H-E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb)."],"pmcid":["PMC9541956"],"funding_grant_id":["WE 1876/13-1"],"pubmed_authors":["Eichele K","Maichle-Mossmer C","Bonath M","Schubert H","Aicher FSW","Sirsch P","Anwander R","Widemann M","Wesemann L"],"additional_accession":[]},"is_claimable":false,"name":"Molecular Ln(III)-H-E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb).","description":"Following the alkane-elimination route, the reaction between tetravalent aryl tintrihydride Ar*SnH<sub>3</sub> and trivalent rare-earth-metallocene alkyls [Cp*<sub>2</sub> Ln(CH{SiMe<sub>3</sub> }<sub>2</sub> )] gave complexes [Cp*<sub>2</sub> Ln(μ-H)<sub>2</sub> SnAr*] implementing a low-valent tin hydride (Ln=Y, Lu; Ar*=2,6-Trip<sub>2</sub> C<sub>6</sub> H<sub>3</sub> , Trip=2,4,6-triisopropylphenyl). The homologous complexes of germanium and lead, [Cp*<sub>2</sub> Ln(μ-H)<sub>2</sub> EAr*] (E = Ge, Pb), were accessed via addition of low-valent [(Ar*EH)<sub>2</sub> ] to the rare-earth-metal hydrides [(Cp*<sub>2</sub> LnH)<sub>2</sub> ]. The lead compounds [Cp*<sub>2</sub> Ln(μ-H)<sub>2</sub> PbAr*] exhibit H/D exchange in reactions with deuterated solvents or dihydrogen.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Aug","modification":"2025-04-22T12:06:34.248Z","creation":"2025-04-06T00:14:58.311Z"},"accession":"S-EPMC9541956","cross_references":{"pubmed":["35620817"],"doi":["10.1002/chem.202201032"]}}