{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Lopez-Moreno A"],"funding":["Ministerio de Ciencia e Innovación","H2020 Marie Skłodowska-Curie Actions"],"pagination":["e202208189"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9544689"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(35)"],"pubmed_abstract":["Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized using ring-closing metathesis, disulfide exchange reaction, H-bonding or direct threading with macrocycles. Here, we describe the encapsulation of single-walled carbon nanotubes within a palladium-based metallosquare. The formation of MINTs was confirmed by a variety of techniques, including high-resolution transmission electron microscopy. We find the making of these MINTs is remarkably sensitive to structural variations of the metallo-assemblies. When a metallosquare with a cavity of appropriate shape and size is used, the formation of the MINT proceeds successfully by both tem"],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Single-Walled Carbon Nanotubes Encapsulated within Metallacycles."],"pmcid":["PMC9544689"],"funding_grant_id":["MSCA-IF-2019-892667","CTQ2017-86060-P","PGC2018-093382-B-I00","PID2020-116661RB-I00","CEX2020-001039-S"],"pubmed_authors":["Ibanez S","Ruiz-Gonzalez L","Perez EM","Sabanes NM","Lopez-Moreno A","Moreno-Da Silva S","Peris E"],"additional_accession":[]},"is_claimable":false,"name":"Single-Walled Carbon Nanotubes Encapsulated within Metallacycles.","description":"Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized using ring-closing metathesis, disulfide exchange reaction, H-bonding or direct threading with macrocycles. Here, we describe the encapsulation of single-walled carbon nanotubes within a palladium-based metallosquare. The formation of MINTs was confirmed by a variety of techniques, including high-resolution transmission electron microscopy. We find the making of these MINTs is remarkably sensitive to structural variations of the metallo-assemblies. When a metallosquare with a cavity of appropriate shape and size is used, the formation of the MINT proceeds successfully by both tem","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Aug","modification":"2025-04-22T01:55:41.52Z","creation":"2025-04-05T20:12:46.073Z"},"accession":"S-EPMC9544689","cross_references":{"pubmed":["35789180"],"doi":["10.1002/anie.202208189"]}}