{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["34(19)"],"submitter":["Liu Y"],"pubmed_abstract":["In this work, we report the hot-injection synthesis of Cs<sub>3</sub>ZnCl<sub>5</sub> colloidal nanocrystals (NCs) with tunable amounts of Cu<sup>+</sup> and Mn<sup>2+</sup> substituent cations. All the samples had a rodlike morphology, with a diameter of ∼14 nm and a length of ∼30-100 nm. Alloying did not alter the crystal structure of the host Cs<sub>3</sub>ZnCl<sub>5</sub> NCs, and Cu ions were mainly introduced in the oxidation state +1 according to X-ray photoelectron and electron paramagnetic resonance spectroscopies. The spectroscopic analysis of unalloyed, Cu-alloyed, Mn-alloyed, and Cu, Mn coalloyed NCs indicated that (i) the Cs<sub>3</sub>ZnCl<sub>5</sub> NCs have a large band gap of ∼5.35 eV; (ii) Cu(I) aliovalent alloying leads to an absorption shoulder/peak at ∼4.8 eV and cyan"],"journal":["Chemistry of materials : a publication of the American Chemical Society"],"pagination":["8603-8612"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9558458"],"repository":["biostudies-literature"],"pubmed_title":["Cu<sup>+</sup> → Mn<sup>2+</sup> Energy Transfer in Cu, Mn Coalloyed Cs<sub>3</sub>ZnCl<sub>5</sub> Colloidal Nanocrystals."],"pmcid":["PMC9558458"],"pubmed_authors":["Infante I","Zaffalon ML","Toso S","Xia Z","De Trizio L","Zito J","Brovelli S","Fanciulli M","Zhu D","Liu Y","Moro F","Cova F","Manna L"],"additional_accession":[]},"is_claimable":false,"name":"Cu<sup>+</sup> → Mn<sup>2+</sup> Energy Transfer in Cu, Mn Coalloyed Cs<sub>3</sub>ZnCl<sub>5</sub> Colloidal Nanocrystals.","description":"In this work, we report the hot-injection synthesis of Cs<sub>3</sub>ZnCl<sub>5</sub> colloidal nanocrystals (NCs) with tunable amounts of Cu<sup>+</sup> and Mn<sup>2+</sup> substituent cations. All the samples had a rodlike morphology, with a diameter of ∼14 nm and a length of ∼30-100 nm. Alloying did not alter the crystal structure of the host Cs<sub>3</sub>ZnCl<sub>5</sub> NCs, and Cu ions were mainly introduced in the oxidation state +1 according to X-ray photoelectron and electron paramagnetic resonance spectroscopies. The spectroscopic analysis of unalloyed, Cu-alloyed, Mn-alloyed, and Cu, Mn coalloyed NCs indicated that (i) the Cs<sub>3</sub>ZnCl<sub>5</sub> NCs have a large band gap of ∼5.35 eV; (ii) Cu(I) aliovalent alloying leads to an absorption shoulder/peak at ∼4.8 eV and cyan","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Oct","modification":"2025-04-18T22:36:57.463Z","creation":"2025-04-07T10:19:25.919Z"},"accession":"S-EPMC9558458","cross_references":{"pubmed":["36248232"],"doi":["10.1021/acs.chemmater.2c01578"]}}