{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Komlyagina VI"],"funding":["Russian Federation for young scientists—Doctors of Sciences","Council for Grants of the President of the Russian Federation"],"pagination":["6961"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9607289"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["27(20)"],"pubmed_abstract":["Self-assembly of (Bu<sub>4</sub>N)<sub>4</sub>[β-Mo<sub>8</sub>O<sub>26</sub>], AgNO<sub>3</sub>, and 2-bis[(2,6-diisopropylphenyl)-imino]acenaphthene (dpp-bian) in DMF solution resulted in the (Bu<sub>4</sub>N)<sub>2</sub>[β-{Ag(dpp-bian)}<sub>2</sub>Mo<sub>8</sub>O<sub>26</sub>] (<b>1</b>) complex. The complex was characterized by single crystal X-ray diffraction (SCXRD), X-ray powder diffraction (XRPD), diffuse reflectance (DR), infrared spectroscopy (IR), and elemental analysis. Comprehensive SCXRD studies of the crystal structure show the presence of Ag<sup>+</sup> in an uncommon coordination environment without a clear preference for Ag-N over Ag-O bonding. Quantum chemical calculations were performed to qualify the nature of the Ag-N/Ag-O interactions and to assign the electronic transitions observed in the UV-Vis absorption spectra. The electrochemical behavior of the complex combines POM and redox ligand signatures. Complex <b>1</b> demonstrates catalytic activity in the electrochemical reduction of CO<sub>2</sub>."],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Trapping of Ag<sup>+</sup> into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry."],"pmcid":["PMC9607289"],"funding_grant_id":["MD-396.2021.1.3"],"pubmed_authors":["Abramov PA","Benassi E","Sokolov MN","Romashev NF","Komlyagina VI","Kokovkin VV","Gushchin AL"],"additional_accession":[]},"is_claimable":false,"name":"Trapping of Ag<sup>+</sup> into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry.","description":"Self-assembly of (Bu<sub>4</sub>N)<sub>4</sub>[β-Mo<sub>8</sub>O<sub>26</sub>], AgNO<sub>3</sub>, and 2-bis[(2,6-diisopropylphenyl)-imino]acenaphthene (dpp-bian) in DMF solution resulted in the (Bu<sub>4</sub>N)<sub>2</sub>[β-{Ag(dpp-bian)}<sub>2</sub>Mo<sub>8</sub>O<sub>26</sub>] (<b>1</b>) complex. The complex was characterized by single crystal X-ray diffraction (SCXRD), X-ray powder diffraction (XRPD), diffuse reflectance (DR), infrared spectroscopy (IR), and elemental analysis. Comprehensive SCXRD studies of the crystal structure show the presence of Ag<sup>+</sup> in an uncommon coordination environment without a clear preference for Ag-N over Ag-O bonding. Quantum chemical calculations were performed to qualify the nature of the Ag-N/Ag-O interactions and to assign the electronic transitions observed in the UV-Vis absorption spectra. The electrochemical behavior of the complex combines POM and redox ligand signatures. Complex <b>1</b> demonstrates catalytic activity in the electrochemical reduction of CO<sub>2</sub>.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Oct","modification":"2025-04-18T21:21:52.502Z","creation":"2025-04-07T09:15:27.315Z"},"accession":"S-EPMC9607289","cross_references":{"pubmed":["36296553"],"doi":["10.3390/molecules27206961"]}}