{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["78(Pt 11)"],"submitter":["Nather C"],"pubmed_abstract":["In the crystal structure of the title compound, {[Ni(NCS)<sub>2</sub>(C<sub>6</sub>H<sub>7</sub>N)<sub>2</sub>]·CH<sub>3</sub>CN} <sub><i>n</i></sub> , the Ni<sup>II</sup> cation is octa-hedrally coordinated by two N-bonding and two S-bonding thio-cyanate anions, as well as two 3-methyl-pyridine coligands, with the thio-cyanate S atoms and the 3-methyl-pyridine N atoms in <i>cis</i>-positions. The metal cations are linked by pairs of thio-cyanate anions into chains that, because of the <i>cis</i>-<i>cis</i>-<i>trans</i> coordination, are corrugated. These chains are arranged in such a way that channels are formed in which disordered aceto-nitrile solvate mol-ecules are located. This overall structural motif is very similar to that observed in Ni(NCS)<sub>2</sub>[4-(boc-amino)-pyridine]<sub"],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["1097-1102"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9638983"],"repository":["biostudies-literature"],"pubmed_title":["Synthesis, crystal structure and properties of <i>catena</i>-poly[[[bis-(3-methyl-pyridine-κ<i>N</i>)nickel(II)]-di-μ-1,3-thio-cyanato] aceto-nitrile monosolvate]."],"pmcid":["PMC9638983"],"pubmed_authors":["Nather C","Krebs C","Jess I"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis, crystal structure and properties of <i>catena</i>-poly[[[bis-(3-methyl-pyridine-κ<i>N</i>)nickel(II)]-di-μ-1,3-thio-cyanato] aceto-nitrile monosolvate].","description":"In the crystal structure of the title compound, {[Ni(NCS)<sub>2</sub>(C<sub>6</sub>H<sub>7</sub>N)<sub>2</sub>]·CH<sub>3</sub>CN} <sub><i>n</i></sub> , the Ni<sup>II</sup> cation is octa-hedrally coordinated by two N-bonding and two S-bonding thio-cyanate anions, as well as two 3-methyl-pyridine coligands, with the thio-cyanate S atoms and the 3-methyl-pyridine N atoms in <i>cis</i>-positions. The metal cations are linked by pairs of thio-cyanate anions into chains that, because of the <i>cis</i>-<i>cis</i>-<i>trans</i> coordination, are corrugated. These chains are arranged in such a way that channels are formed in which disordered aceto-nitrile solvate mol-ecules are located. This overall structural motif is very similar to that observed in Ni(NCS)<sub>2</sub>[4-(boc-amino)-pyridine]<sub","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-25T19:35:28.753Z","creation":"2025-04-06T08:02:56.21Z"},"accession":"S-EPMC9638983","cross_references":{"pubmed":["36380903"],"doi":["10.1107/S2056989022009598"]}}