{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Long W"],"funding":["Advanced Talents of Guangdong University of Petrochemical Technology","Science and Technology Plan Project of Maoming City","Open Fund of Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Guangdong University of Petrochemical Technology"],"pagination":["12881"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9656501"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["23(21)"],"pubmed_abstract":["Nanometer-size Co-ZIF (zeolitic imidazolate frameworks) catalyst was prepared for selective oxidation of toluene to benzaldehyde under mild conditions. The typical characteristics of the metal-organic frameworks (MOFs) material were affirmed by the XRD, SEM, and TEM, the BET surface area of this catalyst was as high as 924.25 m<sup>2</sup>/g, and the diameter of particles was near 200 nm from TEM results. The Co metal was coated with 2-methyl glyoxaline, and the crystalline planes were relatively stable. The reaction temperatures, oxygen pressure, mass amount of N-hydroxyphthalimide (NHPI), and reaction time were discussed. The Co-ZIF catalyst gave the best result of 92.30% toluene conversion and 91.31% selectivity to benzaldehyde under 0.12 MPa and 313 K. The addition of a certain amount "],"journal":["International journal of molecular sciences"],"pubmed_title":["Selective Oxidation of Toluene to Benzaldehyde Using Co-ZIF Nano-Catalyst."],"pmcid":["PMC9656501"],"funding_grant_id":["No.2018B030322017","2019395","2021624","2018rc50"],"pubmed_authors":["Kang X","Long W","Huang Y","Chen Z"],"additional_accession":[]},"is_claimable":false,"name":"Selective Oxidation of Toluene to Benzaldehyde Using Co-ZIF Nano-Catalyst.","description":"Nanometer-size Co-ZIF (zeolitic imidazolate frameworks) catalyst was prepared for selective oxidation of toluene to benzaldehyde under mild conditions. The typical characteristics of the metal-organic frameworks (MOFs) material were affirmed by the XRD, SEM, and TEM, the BET surface area of this catalyst was as high as 924.25 m<sup>2</sup>/g, and the diameter of particles was near 200 nm from TEM results. The Co metal was coated with 2-methyl glyoxaline, and the crystalline planes were relatively stable. The reaction temperatures, oxygen pressure, mass amount of N-hydroxyphthalimide (NHPI), and reaction time were discussed. The Co-ZIF catalyst gave the best result of 92.30% toluene conversion and 91.31% selectivity to benzaldehyde under 0.12 MPa and 313 K. The addition of a certain amount ","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Oct","modification":"2025-04-25T23:39:38.238Z","creation":"2025-04-06T09:22:53.397Z"},"accession":"S-EPMC9656501","cross_references":{"pubmed":["36361670"],"doi":["10.3390/ijms232112881"]}}