{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Huisman BAH"],"funding":["European Research Council","Ministerio de Ciencia e Innovaci?n","Generalitat Valenciana"],"pagination":["5212-5216"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9682476"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["60(7)"],"pubmed_abstract":["Zero-dimensional (0D) mixed-halide hybrid organic-inorganic MA<sub>4</sub>PbX<sub>6</sub>·2H<sub>2</sub>O (MA = CH<sub>3</sub>NH<sub>3</sub><sup>+</sup>; X = Br<sub>1 - <i>x</i></sub>I<i><sub>x</sub></i> with 0 < <i>x</i> < 1) has been synthesized by a solvent-free mechanochemical approach. It has been shown that this 0D phase with sharp absorption features in the near-UV is a hydrated structure, which can be reversibly transformed into the three-dimensional perovskite phase MAPbX<sub>3</sub> by simple thermal annealing (dehydration) in air. This work reveals a new approach to hybrid organic-inorganic perovskites and related 0D structures, which have so far only been thoroughly studied for the inorganic Cs<sub>4</sub>PbX<sub>6</sub> compounds."],"journal":["Inorganic chemistry"],"pubmed_title":["Zero-Dimensional Hybrid Organic-Inorganic Lead Halides and Their Post-Synthesis Reversible Transformation into Three-Dimensional Perovskites."],"pmcid":["PMC9682476"],"funding_grant_id":["MAT2017-88821-R","IDIFEDER/2018/061","EQC2018-004888-P","Prometeu/2020/077","PCI2019-111829-2","834431"],"pubmed_authors":["Huisman BAH","Palazon F","Bolink HJ"],"additional_accession":[]},"is_claimable":false,"name":"Zero-Dimensional Hybrid Organic-Inorganic Lead Halides and Their Post-Synthesis Reversible Transformation into Three-Dimensional Perovskites.","description":"Zero-dimensional (0D) mixed-halide hybrid organic-inorganic MA<sub>4</sub>PbX<sub>6</sub>·2H<sub>2</sub>O (MA = CH<sub>3</sub>NH<sub>3</sub><sup>+</sup>; X = Br<sub>1 - <i>x</i></sub>I<i><sub>x</sub></i> with 0 < <i>x</i> < 1) has been synthesized by a solvent-free mechanochemical approach. It has been shown that this 0D phase with sharp absorption features in the near-UV is a hydrated structure, which can be reversibly transformed into the three-dimensional perovskite phase MAPbX<sub>3</sub> by simple thermal annealing (dehydration) in air. This work reveals a new approach to hybrid organic-inorganic perovskites and related 0D structures, which have so far only been thoroughly studied for the inorganic Cs<sub>4</sub>PbX<sub>6</sub> compounds.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Apr","modification":"2025-04-05T10:57:51.157Z","creation":"2025-04-05T10:57:51.157Z"},"accession":"S-EPMC9682476","cross_references":{"pubmed":["33705124"],"doi":["10.1021/acs.inorgchem.1c00212"]}}