{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Alvarez MA"],"funding":["Ministerio de Ciencia, Innovaci?n y Universidades","Gobierno del Principado de Asturias","Universidad de Oviedo","Agencia Estatal de Investigaci?n","European Regional Development Fund"],"pagination":["18486-18495"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9682477"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(46)"],"pubmed_abstract":["Reactions of the heterometallic MoRe complex [MoReCp(μ-PR*)(CO)<sub>6</sub>] and its MoMn analogue with some small molecules having N-N multiple bonds, such as diazoalkanes and organic azides, were investigated (R* = 2,4,6-C<sub>6</sub>H<sub>2</sub><sup><i>t</i></sup>Bu<sub>3</sub>). Reactions with excess ethyl diazoacetate proceeded slowly and with concomitant denitrogenation to give complexes [MoMCp(μ-η<sup>2</sup><sub>P,C</sub>:κ<sup>2</sup><sub>P,O</sub>-PR*CHCO<sub>2</sub>Et)(CO)<sub>5</sub>], which display a bridging phosphaalkene ligand in a novel μ-η<sup>2</sup>:κ<sup>2</sup> coordination mode, while reactions with other diazoalkanes resulted only in the decomposition of the organic reagent. The MoRe complex reacted with benzyl- or <i>p</i>-tolyl azide at room temperature to give t"],"journal":["Inorganic chemistry"],"pubmed_title":["P-C, P-N, and M-N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles."],"pmcid":["PMC9682477"],"funding_grant_id":["PGC2018-097366-B-I00"],"pubmed_authors":["Garcia ME","Ruiz MA","Cuervo PM","Alvarez MA","Vega P"],"additional_accession":[]},"is_claimable":false,"name":"P-C, P-N, and M-N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles.","description":"Reactions of the heterometallic MoRe complex [MoReCp(μ-PR*)(CO)<sub>6</sub>] and its MoMn analogue with some small molecules having N-N multiple bonds, such as diazoalkanes and organic azides, were investigated (R* = 2,4,6-C<sub>6</sub>H<sub>2</sub><sup><i>t</i></sup>Bu<sub>3</sub>). Reactions with excess ethyl diazoacetate proceeded slowly and with concomitant denitrogenation to give complexes [MoMCp(μ-η<sup>2</sup><sub>P,C</sub>:κ<sup>2</sup><sub>P,O</sub>-PR*CHCO<sub>2</sub>Et)(CO)<sub>5</sub>], which display a bridging phosphaalkene ligand in a novel μ-η<sup>2</sup>:κ<sup>2</sup> coordination mode, while reactions with other diazoalkanes resulted only in the decomposition of the organic reagent. The MoRe complex reacted with benzyl- or <i>p</i>-tolyl azide at room temperature to give t","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-19T16:09:33.579Z","creation":"2025-04-19T16:09:33.579Z"},"accession":"S-EPMC9682477","cross_references":{"pubmed":["36350690"],"doi":["10.1021/acs.inorgchem.2c02720"]}}