{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Shan J"],"funding":["National Natural Science Foundation of China","Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme","Natural Science Foundation of Guangdong Province of China"],"pagination":["e2204192"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9685476"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(33)"],"pubmed_abstract":["Designing dense thick sulfur cathodes to gain high-volumetric/areal-capacity lithium-sulfur batteries (LSBs) in lean electrolytes is extremely desired. Nevertheless, the severe Li<sub>2</sub> S clogging and unclear mechanism seriously hinder its development. Herein, an integrated strategy is developed to manipulate Li<sub>2</sub> S redox kinetics of CoP/MXene catalyst via electron-donor Cu doping. Meanwhile a dense S/Cu<sub>0.1</sub> Co<sub>0.9</sub> P/MXene cathode (density = 1.95 g cm<sup>-3</sup> ) is constructed, which presents a large volumetric capacity of 1664 Ah L<sup>-1</sup> (routine electrolyte) and a high areal capacity of ≈8.3 mAh cm<sup>-2</sup> (lean electrolyte of 5.0 µL mg<sub>s</sub> <sup>-1</sup> ) at 0.1 C. Systematical thermodynamics, kinetics, and theoretical simulati"],"journal":["Advanced science (Weinheim, Baden-Wurttemberg, Germany)"],"pubmed_title":["Unraveling the Atomic-Level Manipulation Mechanism of Li<sub>2</sub> S Redox Kinetics via Electron-Donor Doping for Designing High-Volumetric-Energy-Density, Lean-Electrolyte Lithium-Sulfur Batteries."],"pmcid":["PMC9685476"],"funding_grant_id":["2017","2021A1515011718","51972066"],"pubmed_authors":["Li Y","Shan J","Yue L","Wang W","Zhou W","Wang X","Zhang B"],"additional_accession":[]},"is_claimable":false,"name":"Unraveling the Atomic-Level Manipulation Mechanism of Li<sub>2</sub> S Redox Kinetics via Electron-Donor Doping for Designing High-Volumetric-Energy-Density, Lean-Electrolyte Lithium-Sulfur Batteries.","description":"Designing dense thick sulfur cathodes to gain high-volumetric/areal-capacity lithium-sulfur batteries (LSBs) in lean electrolytes is extremely desired. Nevertheless, the severe Li<sub>2</sub> S clogging and unclear mechanism seriously hinder its development. Herein, an integrated strategy is developed to manipulate Li<sub>2</sub> S redox kinetics of CoP/MXene catalyst via electron-donor Cu doping. Meanwhile a dense S/Cu<sub>0.1</sub> Co<sub>0.9</sub> P/MXene cathode (density = 1.95 g cm<sup>-3</sup> ) is constructed, which presents a large volumetric capacity of 1664 Ah L<sup>-1</sup> (routine electrolyte) and a high areal capacity of ≈8.3 mAh cm<sup>-2</sup> (lean electrolyte of 5.0 µL mg<sub>s</sub> <sup>-1</sup> ) at 0.1 C. Systematical thermodynamics, kinetics, and theoretical simulati","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-18T17:07:42.14Z","creation":"2025-04-07T04:41:54.899Z"},"accession":"S-EPMC9685476","cross_references":{"pubmed":["36202626"],"doi":["10.1002/advs.202204192"]}}