biostudies-literaturePajuelo-Corral OUniversity of the Basque CountryRegional Government of AndalusiaSpanish National Research CouncilBasque Government3977https://www.ebi.ac.uk/biostudies/studies/S-EPMC9694308biostudies-literatureUnknown12(22)The work presented herein reports on the synthesis, structural and physico-chemical characterization, luminescence properties and luminescent sensing activity of a family of isostructural coordination polymers (CPs) with the general formula [Ln₂(μ₄-5Meip)₃(DMF)]_n (where Ln(III) = Sm (<b>1_Sm</b>), Eu (<b>2_Eu</b>), Gd (<b>3_Gd</b>), Tb (<b>4_Tb</b>) and Yb (<b>5_Yb</b>) and 5Meip = 5-methylisophthalate, DMF = N,N-dimethylmethanamide). Crystal structures consist of 3D frameworks tailored by the linkage between infinite lanthanide(III)-carboxylate rods by means of the tetradentate 5Meip ligands. Photoluminescence measurements in solid state at variable temperatures reveal the best-in-class properties based on the capacity of the 5Meip ligand to provide efficient energy transfers to the lanthanide(III) ions, which brings intense emissions in both the visible and near-infrared (NIR) regions. On the one hand, compound <b>5_Yb</b> displays characteristic lanthanide-centered bands in the NIR with sizeable intensity even at room temperature. Among the compounds emitting in the visible region, <b>4_Tb</b> presents a high QY of 63%, which may be explained according to computational calculations. At last, taking advantage of the good performance as well as high chemical and optical stability of <b>4_Tb</b> in water and methanol, its sensing capacity to detect 2,4,6-trinitrophenol (TNP) among other nitroaromatic-like explosives has been explored, obtaining high detection capacity (with K_sv around 10⁵ M^-1), low limit of detection (in the 10^-6-10^-7 M) and selectivity among other molecules (especially in methanol).Nanomaterials (Basel, Switzerland)Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules.PMC9694308GIU20/028FQM-394 and B-FQM-734-UGR20 and B-FQM-478-UGR20IT1755-22 and IT1500-22PGC2018-102052-A-C22, PGC2018-102052-B-C21 and PID2020-117344RB-I00Razquin-Bobillo LGarcia JARodriguez-Dieguez APajuelo-Corral OSalinas-Castillo AChoquesillo-Lazarte DHernandez RRojas SCepeda JfalseLanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules.The work presented herein reports on the synthesis, structural and physico-chemical characterization, luminescence properties and luminescent sensing activity of a family of isostructural coordination polymers (CPs) with the general formula [Ln₂(μ₄-5Meip)₃(DMF)]_n (where Ln(III) = Sm (<b>1_Sm</b>), Eu (<b>2_Eu</b>), Gd (<b>3_Gd</b>), Tb (<b>4_Tb</b>) and Yb (<b>5_Yb</b>) and 5Meip = 5-methylisophthalate, DMF = N,N-dimethylmethanamide). Crystal structures consist of 3D frameworks tailored by the linkage between infinite lanthanide(III)-carboxylate rods by means of the tetradentate 5Meip ligands. Photoluminescence measurements in solid state at variable temperatures reveal the best-in-class properties based on the capacity of the 5Meip ligand to provide efficient energy transfers to the lanthanide(III) ions, which brings intense emissions in both the visible and near-infrared (NIR) regions. On the one hand, compound <b>5_Yb</b> displays characteristic lanthanide-centered bands in the NIR with sizeable intensity even at room temperature. Among the compounds emitting in the visible region, <b>4_Tb</b> presents a high QY of 63%, which may be explained according to computational calculations. At last, taking advantage of the good performance as well as high chemical and optical stability of <b>4_Tb</b> in water and methanol, its sensing capacity to detect 2,4,6-trinitrophenol (TNP) among other nitroaromatic-like explosives has been explored, obtaining high detection capacity (with K_sv around 10⁵ M^-1), low limit of detection (in the 10^-6-10^-7 M) and selectivity among other molecules (especially in methanol).2022-01-01T00:00:00Z2022 Nov2024-10-18T09:22:28.321Z2024-10-18T09:22:28.321ZS-EPMC96943083643226310.3390/nano12223977