{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["13(46)"],"submitter":["Wang L"],"pubmed_abstract":["Singlet fission (SF) has drawn tremendous attention as a multiexciton generation process that could mitigate the thermal loss and boost the efficiency of solar energy conversion. Although a SF-based solar cell with an EQE above 100% has already been fabricated successfully, the practical efficiency of the corresponding devices is plagued by the limited scope of SF materials. Therefore, it is of great importance to design and develop new SF-capable compounds aiming at practical device application. In the current contribution, via a π-expanded strategy, we presented a new series of robust SF chromophores based on polycyclic DPP derivatives, Ex-DPPs. Compared to conventional DPP molecules, Ex-DPPs feature strong absorption with a fivefold extinction coefficient, good molecular rigidity to eff"],"journal":["Chemical science"],"pagination":["13907-13913"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9710207"],"repository":["biostudies-literature"],"pubmed_title":["Robust singlet fission process in strong absorption π-expanded diketopyrrolopyrroles."],"pmcid":["PMC9710207"],"pubmed_authors":["Yan L","Yao J","Zhang D","Zhang M","Wang G","Guo S","Shao JY","Wang L","Liu Z","Jiang W","Wang S","Fu H","Miao Y","Zhong YW"],"additional_accession":[]},"is_claimable":false,"name":"Robust singlet fission process in strong absorption π-expanded diketopyrrolopyrroles.","description":"Singlet fission (SF) has drawn tremendous attention as a multiexciton generation process that could mitigate the thermal loss and boost the efficiency of solar energy conversion. Although a SF-based solar cell with an EQE above 100% has already been fabricated successfully, the practical efficiency of the corresponding devices is plagued by the limited scope of SF materials. Therefore, it is of great importance to design and develop new SF-capable compounds aiming at practical device application. In the current contribution, via a π-expanded strategy, we presented a new series of robust SF chromophores based on polycyclic DPP derivatives, Ex-DPPs. Compared to conventional DPP molecules, Ex-DPPs feature strong absorption with a fivefold extinction coefficient, good molecular rigidity to eff","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-18T17:13:37.03Z","creation":"2025-04-07T04:46:32.06Z"},"accession":"S-EPMC9710207","cross_references":{"pubmed":["36544745"],"doi":["10.1039/d2sc05580e"]}}