{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["13(1)"],"submitter":["Shang S"],"pubmed_abstract":["Conductive metal-organic frameworks (MOFs) have performed well in the fields of energy and catalysis, among which two-dimensional (2D) and three-dimensional (3D) MOFs are well-known. Here, we have synthesized a one-dimensional (1D) conductive metal-organic framework (MOF) in which hexacoordinated 1,5-Diamino-4,8-dihydroxy-9,10-anthraceneedione (DDA) ligands are connected by double Cu ions, resulting in nanoribbon layers with 1D π-d conjugated nanoribbon plane and out-of-plane π-π stacking, which facilitates charge transport along two dimensions. The DDA-Cu as a highly conductive n-type MOF has high crystalline quality with a conductivity of ~ 9.4 S·m<sup>-1</sup>, which is at least two orders of magnitude higher than that of conventional 1D MOFs. Its electrical band gap (E<sub>g</sub>) and"],"journal":["Nature communications"],"pagination":["7599"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9734122"],"repository":["biostudies-literature"],"pubmed_title":["A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers."],"pmcid":["PMC9734122"],"pubmed_authors":["Liu Y","Zou Y","Du C","Liu M","Chen J","Dong J","Gao W","Wang X","Shang S"],"additional_accession":[]},"is_claimable":false,"name":"A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers.","description":"Conductive metal-organic frameworks (MOFs) have performed well in the fields of energy and catalysis, among which two-dimensional (2D) and three-dimensional (3D) MOFs are well-known. Here, we have synthesized a one-dimensional (1D) conductive metal-organic framework (MOF) in which hexacoordinated 1,5-Diamino-4,8-dihydroxy-9,10-anthraceneedione (DDA) ligands are connected by double Cu ions, resulting in nanoribbon layers with 1D π-d conjugated nanoribbon plane and out-of-plane π-π stacking, which facilitates charge transport along two dimensions. The DDA-Cu as a highly conductive n-type MOF has high crystalline quality with a conductivity of ~ 9.4 S·m<sup>-1</sup>, which is at least two orders of magnitude higher than that of conventional 1D MOFs. Its electrical band gap (E<sub>g</sub>) and","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2025-04-05T11:51:38.753Z","creation":"2025-04-05T11:51:38.753Z"},"accession":"S-EPMC9734122","cross_references":{"pubmed":["36494377"],"doi":["10.1038/s41467-022-35315-0"]}}