{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["7(49)"],"submitter":["Gys N"],"pubmed_abstract":["Amino-alkylphosphonic acid-grafted TiO<sub>2</sub> materials are of increasing interest in a variety of applications such as metal sorption, heterogeneous catalysis, CO<sub>2</sub> capture, and enzyme immobilization. To date, systematic insights into the synthesis-properties-performance correlation are missing for such materials, albeit giving important know-how towards their applicability and limitations. In this work, the impact of the chain length and modification conditions (concentration and temperature) of amino-alkylphosphonic acid-grafted TiO<sub>2</sub> on the surface properties and adsorption performance of palladium is studied. Via grafting with aminomethyl-, 3-aminopropyl-, and 6-aminohexylphosphonic acid, combined with the spectroscopic techniques (DRIFT, <sup>31</sup>P NMR, X"],"journal":["ACS omega"],"pagination":["45409-45421"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9753204"],"repository":["biostudies-literature"],"pubmed_title":["Amino-Alkylphosphonate-Grafted TiO<sub>2</sub>: How the Alkyl Chain Length Impacts the Surface Properties and the Adsorption Efficiency for Pd."],"pmcid":["PMC9753204"],"pubmed_authors":["An R","Wyns K","Adriaensens P","Hauffman T","Meynen V","Gys N","Vogelsang D","Blockhuys F","Baert K","Pawlak B","Mullens S","Vansant A","Michielsen B"],"additional_accession":[]},"is_claimable":false,"name":"Amino-Alkylphosphonate-Grafted TiO<sub>2</sub>: How the Alkyl Chain Length Impacts the Surface Properties and the Adsorption Efficiency for Pd.","description":"Amino-alkylphosphonic acid-grafted TiO<sub>2</sub> materials are of increasing interest in a variety of applications such as metal sorption, heterogeneous catalysis, CO<sub>2</sub> capture, and enzyme immobilization. To date, systematic insights into the synthesis-properties-performance correlation are missing for such materials, albeit giving important know-how towards their applicability and limitations. In this work, the impact of the chain length and modification conditions (concentration and temperature) of amino-alkylphosphonic acid-grafted TiO<sub>2</sub> on the surface properties and adsorption performance of palladium is studied. Via grafting with aminomethyl-, 3-aminopropyl-, and 6-aminohexylphosphonic acid, combined with the spectroscopic techniques (DRIFT, <sup>31</sup>P NMR, X","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2025-04-18T16:31:46.805Z","creation":"2025-04-07T03:47:21.877Z"},"accession":"S-EPMC9753204","cross_references":{"pubmed":["36530305"],"doi":["10.1021/acsomega.2c06020"]}}