{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Lianglu J"],"funding":["Natural Science Foundation of Henan Province","National Natural Science Foundation of China","China Postdoctoral Science Foundation"],"pagination":["15580"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9779595"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["23(24)"],"pubmed_abstract":["In recent years, incredible endeavors have been devoted to the design and self-assembly of discrete metal-organic cages (MOCs) with expanding intricacy and functionality. The controlled synthesis of metal-organic supramolecular cages with large branched chains remains an interesting and challenging work in supramolecular chemistry. Herein, a tetrahedral metal-organic supramolecular cage (Zn<sup>II</sup><sub>4</sub>L<sub>4</sub>) containing 12 dendritic carbazole arms is unprecedentedly constructed through coordination-driven subcomponent self-assembly and characterized in different ways. Interestingly, tetrahedral supramolecular <b>Cage-1</b> exhibited the potential for aggregation-induced emission (AIE) performance and stimulus-responsive luminescence features, and it achieved color-tunable photoluminescence due to the introduction of dendritic carbazole arms. Crucially, owing to the great photophysical properties of <b>Cage-1</b> in solution, <b>Cage-1</b> was enabled to act as a fluorescent ink for the vapor-responsive recording and wiping of information."],"journal":["International journal of molecular sciences"],"pubmed_title":["Synthesis of a Tetrahedral Metal-Organic Supramolecular Cage with Dendritic Carbazole Arms."],"pmcid":["PMC9779595"],"funding_grant_id":["202300410477","2021M692905","22101267, 21803059, U1904212, and U2004191"],"pubmed_authors":["Zhang HY","Shi L","Song MP","Hao XQ","Hu W","Zhu X","Lianglu J"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis of a Tetrahedral Metal-Organic Supramolecular Cage with Dendritic Carbazole Arms.","description":"In recent years, incredible endeavors have been devoted to the design and self-assembly of discrete metal-organic cages (MOCs) with expanding intricacy and functionality. The controlled synthesis of metal-organic supramolecular cages with large branched chains remains an interesting and challenging work in supramolecular chemistry. Herein, a tetrahedral metal-organic supramolecular cage (Zn<sup>II</sup><sub>4</sub>L<sub>4</sub>) containing 12 dendritic carbazole arms is unprecedentedly constructed through coordination-driven subcomponent self-assembly and characterized in different ways. Interestingly, tetrahedral supramolecular <b>Cage-1</b> exhibited the potential for aggregation-induced emission (AIE) performance and stimulus-responsive luminescence features, and it achieved color-tunable photoluminescence due to the introduction of dendritic carbazole arms. Crucially, owing to the great photophysical properties of <b>Cage-1</b> in solution, <b>Cage-1</b> was enabled to act as a fluorescent ink for the vapor-responsive recording and wiping of information.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2025-04-04T08:45:31.105Z","creation":"2025-04-04T08:45:31.105Z"},"accession":"S-EPMC9779595","cross_references":{"pubmed":["36555222"],"doi":["10.3390/ijms232415580"]}}