{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["27(24)"],"submitter":["Brol A"],"pubmed_abstract":["Deamination of 1-aminoalkylphosphonic acids in the reaction with HNO<sub>2</sub> (generated \"in situ\" from NaNO<sub>2</sub>) yields a mixture of substitution products (1-hydroxyalkylphosphonic acids), elimination products (vinylphosphonic acid derivatives), rearrangement and substitution products (2-hydroxylkylphosphonic acids) as well as H<sub>3</sub>PO<sub>4</sub>. The variety of formed reaction products suggests that 1-phosphonoalkylium ions may be intermediates in such deamination reactions."],"journal":["Molecules (Basel, Switzerland)"],"pagination":["8849"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9783495"],"repository":["biostudies-literature"],"pubmed_title":["Deamination of 1-Aminoalkylphosphonic Acids: Reaction Intermediates and Selectivity."],"pmcid":["PMC9783495"],"pubmed_authors":["Brol A","Olszewski TK"],"additional_accession":[]},"is_claimable":false,"name":"Deamination of 1-Aminoalkylphosphonic Acids: Reaction Intermediates and Selectivity.","description":"Deamination of 1-aminoalkylphosphonic acids in the reaction with HNO<sub>2</sub> (generated \"in situ\" from NaNO<sub>2</sub>) yields a mixture of substitution products (1-hydroxyalkylphosphonic acids), elimination products (vinylphosphonic acid derivatives), rearrangement and substitution products (2-hydroxylkylphosphonic acids) as well as H<sub>3</sub>PO<sub>4</sub>. The variety of formed reaction products suggests that 1-phosphonoalkylium ions may be intermediates in such deamination reactions.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2025-04-22T13:16:33.382Z","creation":"2025-04-06T00:39:05.914Z"},"accession":"S-EPMC9783495","cross_references":{"pubmed":["36557979"],"doi":["10.3390/molecules27248849"]}}