{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Fang Y"],"funding":["Nation Natural Science Foundation of China","China Postdoctoral Science Foundation"],"pagination":["e2205680"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9798975"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(36)"],"pubmed_abstract":["Inducing new phases of transition metal dichalcogenides by controlling the d-electron-count has attracted much interest due to their novel structures and physicochemical properties. 1T'' ReSe<sub>2</sub> is a promising candidate for sodium storage, but the low electronic conductivity and limited active sites hinder its electrochemical capacity. Herein, new-phase 1T' Re<sub>0.75</sub> V<sub>0.25</sub> Se<sub>2</sub> crystals (P2/m) with zig-zag chains are successfully synthesized. The 1T''-1T' phase transition results from the electronic reorganization of 5d orbitals via electron extraction after V-atom doping. The electrical conductivity of 1T' Re<sub>0.75</sub> V<sub>0.25</sub> Se<sub>2</sub> is 2.7 × 10<sup>5</sup> times higher than that of 1T'' ReSe<sub>2</sub> . Moreover, density funct"],"journal":["Advanced science (Weinheim, Baden-Wurttemberg, Germany)"],"pubmed_title":["Electron-Extraction Engineering Induced 1T''-1T' Phase Transition of Re<sub>0.75</sub> V<sub>0.25</sub> Se<sub>2</sub> for Ultrafast Sodium Ion Storage."],"pmcid":["PMC9798975"],"funding_grant_id":["22025502","BX2021329","21975051","2021M693261","52103353"],"pubmed_authors":["Fang Y","Lv Z","Huang F","Lv X","Wang Y","Zheng G"],"additional_accession":[]},"is_claimable":false,"name":"Electron-Extraction Engineering Induced 1T''-1T' Phase Transition of Re<sub>0.75</sub> V<sub>0.25</sub> Se<sub>2</sub> for Ultrafast Sodium Ion Storage.","description":"Inducing new phases of transition metal dichalcogenides by controlling the d-electron-count has attracted much interest due to their novel structures and physicochemical properties. 1T'' ReSe<sub>2</sub> is a promising candidate for sodium storage, but the low electronic conductivity and limited active sites hinder its electrochemical capacity. Herein, new-phase 1T' Re<sub>0.75</sub> V<sub>0.25</sub> Se<sub>2</sub> crystals (P2/m) with zig-zag chains are successfully synthesized. The 1T''-1T' phase transition results from the electronic reorganization of 5d orbitals via electron extraction after V-atom doping. The electrical conductivity of 1T' Re<sub>0.75</sub> V<sub>0.25</sub> Se<sub>2</sub> is 2.7 × 10<sup>5</sup> times higher than that of 1T'' ReSe<sub>2</sub> . Moreover, density funct","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2025-04-04T21:05:05.816Z","creation":"2025-04-04T21:05:05.816Z"},"accession":"S-EPMC9798975","cross_references":{"pubmed":["36372525"],"doi":["10.1002/advs.202205680"]}}