{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["28(56)"],"submitter":["Morris LJ"],"funding":["Deutsche Forschungsgemeinschaft"],"pubmed_abstract":["In the presence of TMEDA (N,N,N',N'-tetramethylethylenediamine), partially deaggregated zinc dihydride as hydrocarbon suspensions react with the gallium(I) compound [(BDI)Ga] (I, BDI={HC(C(CH<sub>3</sub> )N(2,6-iPr<sub>2</sub> -C<sub>6</sub> H<sub>3</sub> ))<sub>2</sub> }<sup>-</sup> ) by formal oxidative addition of a Zn-H bond to the gallium(I) centre. Dissociation of the labile TMEDA ligand in the resulting complex [(BDI)Ga(H)-(H)Zn(tmeda)] (1) facilitates insertion of a second equiv. of I into the remaining Zn-H to form a thermally sensitive trinuclear species [{(BDI)Ga(H)}<sub>2</sub> Zn] (2). Compound 1 exchanges with polymeric zinc dideuteride [ZnD<sub>2</sub> ]<sub>n</sub> in the presence of TMEDA, and with compounds I and 2 via sequential and reversible ligand dissociation and gal"],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pagination":["e202201480"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9804236"],"repository":["biostudies-literature"],"pubmed_title":["Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)-Centre: Labile Mono- and Bis(hydridogallyl)zinc Complexes."],"pmcid":["PMC9804236"],"pubmed_authors":["Morris LJ","Rajeshkumar T","Okuda J","Maron L"],"additional_accession":[]},"is_claimable":false,"name":"Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)-Centre: Labile Mono- and Bis(hydridogallyl)zinc Complexes.","description":"In the presence of TMEDA (N,N,N',N'-tetramethylethylenediamine), partially deaggregated zinc dihydride as hydrocarbon suspensions react with the gallium(I) compound [(BDI)Ga] (I, BDI={HC(C(CH<sub>3</sub> )N(2,6-iPr<sub>2</sub> -C<sub>6</sub> H<sub>3</sub> ))<sub>2</sub> }<sup>-</sup> ) by formal oxidative addition of a Zn-H bond to the gallium(I) centre. Dissociation of the labile TMEDA ligand in the resulting complex [(BDI)Ga(H)-(H)Zn(tmeda)] (1) facilitates insertion of a second equiv. of I into the remaining Zn-H to form a thermally sensitive trinuclear species [{(BDI)Ga(H)}<sub>2</sub> Zn] (2). Compound 1 exchanges with polymeric zinc dideuteride [ZnD<sub>2</sub> ]<sub>n</sub> in the presence of TMEDA, and with compounds I and 2 via sequential and reversible ligand dissociation and gal","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Oct","modification":"2026-03-16T02:19:26.697Z","creation":"2025-04-05T12:09:03.625Z"},"accession":"S-EPMC9804236","cross_references":{"pubmed":["35819049"],"doi":["10.1002/chem.202201480"]}}