biostudies-literatureUnknown17(19)Wang CChina Scholarship CouncilTreatment of N-methyl-S,S-diaryl sulfoximines with methyl trifluoromethanesulfonate provides bench-stable sulfoxinium salts in excellent yields. Applying them in Sonogashira-, Heck- and Suzuki-type cross-coupling reactions leads to the corresponding products by sequential C-S bond cleavage and C-C bond formation. Electronic factors induced by substituents on the S-aryl groups govern the coupling efficiency.Chemistry, an Asian journale202200828https://www.ebi.ac.uk/biostudies/studies/S-EPMC9804342biostudies-literatureThe Preparation of Diaryl Sulfoxinium Triflates and Their Application in Palladium-Catalyzed Cross-Coupling Reactions.PMC9804342Wang CRissanen KTruong KNKong DWang XBolm CfalseThe Preparation of Diaryl Sulfoxinium Triflates and Their Application in Palladium-Catalyzed Cross-Coupling Reactions.Treatment of N-methyl-S,S-diaryl sulfoximines with methyl trifluoromethanesulfonate provides bench-stable sulfoxinium salts in excellent yields. Applying them in Sonogashira-, Heck- and Suzuki-type cross-coupling reactions leads to the corresponding products by sequential C-S bond cleavage and C-C bond formation. Electronic factors induced by substituents on the S-aryl groups govern the coupling efficiency.2022-01-01T00:00:00Z2022 Oct2025-04-05T12:09:15.814Z2025-04-05T12:09:15.814ZS-EPMC98043423594777810.1002/asia.202200828